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- E-ISSN 2288-8985
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Nanoconfinement effects of MCM-41 on the thermal decomposition of metal borohydrides
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2018, v.31 no.1, pp.1-6
https://doi.org/10.5806/AST.2018.31.1.1
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(2018). Nanoconfinement effects of MCM-41 on the thermal decomposition of metal borohydrides. Analytical Science and Technology, 31(1), 1-6, https://doi.org/10.5806/AST.2018.31.1.1
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Abstract
We used differential scanning calorimetry and a thermogravimetric analysis to investigate the effect of being confined in mesoporous MCM-41 on the decomposition of lithium borohydride and magnesium borohydride when heated. The confinement did not cause a phase transition of the metal borohydrides inside MCM-41, but did lower their decomposition temperature. With the exception of a lowering of the temperature, the decomposition reaction mechanism of the metal borohydrides was nearly the same for both the bulk and confined samples.
- keywords
- Hydrogen storage, Dehydrogenation, Lithium borohydride <TEX>$LiBH_4$</TEX>, Magnesium borohydride <TEX>$Mg(BH_4)_2$</TEX>, MCM-41
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