ISSN : 1225-3480
진주의 감별기법상 UV-Vis의 흡수 스펙트럼 분석과 반사율 분석은 흑진주의 색깔이 자연 그대로인지 아니면 처리에 의한 결과인지를 구별하는데 중요한 요소가 된다. 또한 ED-XRF을 이용한 미량 원소 분석은 진주가 해수산인지 담수산인지 여부와 은염 또는 염색 처리 유무를 판단하는데 이용될 수 있다. 본 연구에서는 은염 또는 염색 처리되지 않은 여러 종류(담수양식진주, 아코야양식진주, 타히티흑양식진주)의 진주에 은염처리를 한 결과, 은 이온 고유의 스펙트럼이 진주 고유의 스펙트럼에 영향을 주어 UV-Vis흡수 스펙트럼이 변화되었다. 또한 반사율도 은염처리하기 전보다 낮아짐을 알 수 있었다. 특히 자연 색상의 타히티흑양식진주의 경우 400 nm, 500nm, 700 nm의 고유 흡수 스펙트럼을 갖고 있었으며, 자연색상의 담수흑양식진주의 경우 380-400 nm, 480-500 nm 두 개의 특징적인 흡수 스펙트럼으로 나타났다. 자연 색상의 담수흑진주에서는 자연 색상의 타히티흑진주와는 달리 700nm의 흡수 스펙트럼이 관찰되지 않았다. 직접 은염처리한 진주 9 개를 ED-XRF를 이용하여 분석한 결과, 처리시간이 증가함에 따라 진주 층에 침투된 은의 함량이 점차로 증가했음을 알 수 있었다. 또한 시중에서 구입한 흑진주 18 개를 분석한 결과, 은 이온의 상대 함유량이 약 0.1%를 경계로 은염 또는 염색 처리 여부를 판단하는 데 도움을 줄 수 있을 것으로 생각되었다.
Freshwater cultured pearls show generally white, orange pink and purple series. This study suggests the identification point of freshwater black cultured pearl based on comparative analysis of a rare freshwater cultured pearl of natural black color which is produced less than 0.1% from freshwater cultured pearl production. Various identification methods has somehow been established for other black cultured pearls (treated Akoya black cultured pearl, natural Tahiti black cultured pearl, treated Tahiti black cultured pearl and treated Freshwater black cultured pearl). Naturally colored Freshwater black cultured pearl has two characteristic absorption patterns in UV-Vis spectra, which are 380 nm-400 nm and 480 nm-500 nm. Unlike naturally colored Tahiti black cultured pearl, the absorption spectrum at 700 nm cannot be found from freshwater black cultured pearl. It can be concluded that the color was not processed due to its very high reflective Index (70%). Judging from the contents of Mn and Sr elements found from ED-XRF analysis, it is possible to identify this as freshwater cultured pearl. Since the content of Ag is ranged under 0.1%, it seems to be that the possibility of silver nitrate treatment is very low. Moreover, by conducting silver nitrate treatment on series of white Akoya cultured pearl, freshwater cultured pearl and Tahiti black cultured pearl of light black or gray color, the result of this study provides a way to identify whether black color pearls of any origin found in marketplace are treated or not.
Akamatsu, S, (2001) The current status of Chinese freshwater cultured pearls, Gems & Gemology
Habermann, D, (2001) Investigation of manganese in salt- and freshwater pearls, Nuclear Instruments and Methods in Physics Research B
Huang, F, (2003) Pearl cultivation in Donggou, Ezhou, Hubei, and cathodoluminescence of cultured pearls, Gemological Association and Gem Testing Laboratory of Great Britain
Kenneth, S, (2000) Characteristics of nuclei in Chinese freshwater cultured pearls, Gem & Gemology
Komathu, H, (1992) Pearl Identification Theory, Gemological Association of All Japan, Tokyo
Komathu, H, (2002) Knowledge and Sale-technique of Pearl, Senken Newspaper Company, Tokyo
Li, L, (2001) Cultured pearls and colour-changed cultured pearls, Raman spectra Gemmological Association and Gem Testing Laboratory of Great Britain
Muller,A, (1997) Cultured Pearl: The First Hundred Years, Golay Buchel Group International Ad Co. Ltd., Hong Kong.
Oh, J.U, (2003) The estimation characteristics of cultured pearls, Journal of the Korean Crystal Growth and Crystal Technology
Wada K.J, (1982) Science of Pearl, Pearl Newspaper Company, Tokyo
Zhang, X.Y, (2003) Synthesis of silver oxide nano-scale thin films and photo-activated dynamic luminescence from their nanoparticles, Acta Physics-Chemistry Sinica