- P-ISSN 2233-4203
- E-ISSN 2093-8950
- 권한신청
- P-ISSN2233-4203
- E-ISSN2093-8950
- ESCI
논문 상세
Home > 논문 상세
Experimental Study for the Identification of the Nascent Product of OH Heterogeneous Reaction with NaCl using Chemical Ionization Mass Spectrometry
Mass Spectrometry Letters / Mass Spectrometry Letters, (P)2233-4203; (E)2093-8950
2012, v.3 no.4, pp.108-111
https://doi.org/10.5478/MSL.2012.3.4.108
(Korea Atomic Energy Research Institute)
(University of California)
(University of California)
(University of California)
(University of California)
Park,
J. H.,
Ivanov,
A. V.,
&
Molina,
M.
J.
(2012). . Mass Spectrometry Letters, 3(4), 108-111, https://doi.org/10.5478/MSL.2012.3.4.108
- 다운로드 수
- 조회수
Abstract
An experimental study on the nascent product of the OH heterogeneous reaction with NaCl was performed under dryand wet conditions using a bead-filled flow tube system coupled to a high-pressure chemical ionization mass spectrometer. Theozone concentration in the flow tube for the atomic hydrogen removal was varied in order to control the conversion reaction ofmolecular chlorine into HCl for the identification of the nascent product. The mass spectrometric observation was that the O3introduction reduced the concentration HCl, while it increased the concentration of Cl2 and ClO. Based on the experimentalresults, we suggest that the nascent product of the titled reaction is gaseous Cl2, which is followed by fast conversion into HCl inpresence of H. No significant difference in the concentration profile between under dry and wet (RH = 2%) conditions wasobserved.
- keywords
- OH, Heterogeneou reaction, Atmospheric chemistry, CIMS
참고문헌
1
Hanson, D. R. (1992). . J. Phys. Chem, 96, 4979-.
2
Cooper, P. L. (1996). . J. Phys. Chem, 100, 2249-.
3
Ivanov, A. V. (1997). . Ann. Geophys, 14, 659-.
4
Bertram, A. K. (2001). . J. Phys.Chem. A, 105, 9415-.
5
Park, J.-H. (2008). . J. Phys. Chem. A, 112, 6968-.
6
Park, J.-H. (2009). . Geophys. Res. Lett, 36, L02802-.
7
DeMore, W. B. Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling;Evaluation Number 12, JPL Publication 97-4.
8
Huey, L. G. (1995). . J. Phys. Chem, 99, 5001-.
9
Berho, F. (1999). . J. Phys. Chem. A, 103, 5501-.
10
Yu, H. G. (1997). . J. Chem. Soc. Faraday. Trans, 93, 2651-.
11
Leu, M.-T. (1989). . J. Phys. Chem, 93, 5778-.
12
Bodenstein, M. (1929). . Phys. Chem. Abt. B, 5, 209-.
13
Zasypkin, A. Y. (1997). . Kinet. Catal, 38, 772-.
14
Oum, K. W. (1998). . Science, 279, 74-.
15
Finlayson-Pitts, B. J. (2000). . J. Phys. Chem. A, 104, 11463-.
16
Baulch, D. L. (1981). . J. Phys. Chem. Ref. Data, 10, 1-.
17
Bryukov, M. G. (2004). . J. Phys. Chem. A, 108, 10464-.
- 투고일Submission Date
- 2012-12-11
- 수정일Revised Date
- 2012-12-18
- 게재확정일Accepted Date
- 2012-12-18
권호 내 다른 논문
- Syringe Infusion-based Contactless Atmospheric Pressure Ionization Mass Spectrometry for Small and Large Biomolecules
- Quantitative Phosphoproteomics of the Human Neural Stem Cell Differentiation into Oligodendrocyte by Mass Spectrometry
- Analysis of Photodegradation Products of Organic Photochromes by LC/MS
- Effects of Mollugin on Hepatic Cytochrome P450 in Male ICR Mice as Determined by Liquid Chromatography/Tandem Mass Spectrometry
- Experimental Study for the Identification of the Nascent Product of OH Heterogeneous Reaction with NaCl using Chemical Ionization Mass Spectrometry
- more
추천 논문
학술지 홈페이지 이용 환경은 크롬 브라우저 사용을 권장합니다.