- P-ISSN 2233-4203
- E-ISSN 2093-8950
- 권한신청
- P-ISSN2233-4203
- E-ISSN2093-8950
논문 상세
Home > 논문 상세
Accurate Measurement of Isotope Amount Ratios of Lead in Bronze with Multicollector Inductively Coupled Plasma Mass Spectrometry
Mass Spectrometry Letters / Mass Spectrometry Letters, (P)2233-4203; (E)2093-8950
2013, v.4 no.4, pp.87-90
https://doi.org/10.5478/MSL.2013.4.4.87
(Korea Research Institute of Standard and Science)
(Korea Research Institute of Standard and Science)
(Korea Research Institute of Standard and Science)
(Korea Research Institute of Standard and Science)
(Pusan National University)
(Korea Research Institute of Standard and Science)
(Korea Research Institute of Standard and Science)
(Korea Research Institute of Standard and Science)
(Pusan National University)
Lee,
K.,
Kim,
J.,
Yim,
Y.,
Hwang,
E.,
&
Kim,
T.
K.
(2013). . Mass Spectrometry Letters, 4(4), 87-90, https://doi.org/10.5478/MSL.2013.4.4.87
- 다운로드 수
- 조회수
Abstract
Isotope amount ratios of lead in a bronze sample have been successfully determined using multicollector inductivelycoupled plasma mass spectrometry (MC-ICP-MS). Matrix separation conditions were tested and optimized using ion exchangechromatography with anion-exchange resin, AG1-X8, and sequential elution of the 0.5 M HBr and 7 M HNO3 to separate leadfrom very high contents of copper and tin in bronze matrix. Mercury was also removed efficiently in the optimized separationcondition. The instrumental isotope fractionation of lead in the MC-ICP-MS measurement was corrected by the external standardsample bracketing method using an external standard, NIST SRM 981 lead common isotope ratio standard followed by correctionof procedure blank to obtain reliable isotope ratios of lead. The isotope ratios, 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, and208Pb/206Pb, of lead were determined as 18.0802 ± 0.0114, 15.5799 ± 0.0099, 38.0853 ± 0.0241, and 2.1065 ± 0.0004, respectively,and the determined isotope ratios showed good agreement with the reference values of an international comparison for thesame sample within the stated uncertainties.
- keywords
- isotope ratio, lead, MC-ICP-MS, bronze, matrix separation
참고문헌
1
Cohen, E. R. (2008). Quantities, Units and Symbols in Physical Chemistry, IUPAC Green Book:IUPAC & RSC Publishing.
2
Vanhaecke, F. (2012). Isotopic Analysis: Fundamentals and Applications Using ICP-MS:Wiley- VCH Verlag & Co. KGaA.
3
Balcaen, L. (2010). . Spectrochim. Acta, Part B, 65, 769-.
4
Cheng, H. (2010). . Environmental Pollution, 158, 1134-.
5
Díaz-Somoano, M. (2009). . Environ. Sci. Technol, 43, 1078-.
6
Heumann, K. G. (1998). . J. Anal. At. Spectrom, 13, 1001-.
7
Albarède, F. (2004). . Reviews in Mineralogy & Geochemistry, 55, 113-.
8
Yang, L. (2009). . Mass Spectrom. Rev, 28, 990-.
9
Weyer, S. (2003). . Int. J. Mass Spectrom, 226, 355-.
10
Andersen, T. (1962). . Acta Chemica Scandinavica, 16, 849-.
11
Strelow, F. W. E. (1966). . Anal. Chem, 38, 545-.
12
Guide to the Expression of Uncertainty in Measurement.
- 투고일Submission Date
- 2013-12-13
- 수정일Revised Date
- 2013-12-19
- 게재확정일Accepted Date
- 2013-12-19
권호 내 다른 논문
- Discovery of Urinary Biomarkers in Patients with Breast Cancer Based on Metabolomics
- Structural Analysis of the Cu-binding Site in the [Cu·dCMP·dCMP-H]1− Complex
- Charge-Directed Peptide Backbone Dissociations of o-TEMPO-Bz-C(O)- Peptides
- Development of Gas Chromatography/ Mass Spectrometry for the Determination of Essential Fatty Acids in Food Supplemental Oil Products
- General Fragmentations of Alkaloids in Electrospray Ionization Tandem Mass Spectrometry
- Development of a Four-way Interface for Online Capillary Isoelectric Focusing-Electrospray-Mass Spectrometry (CIEF-ESI-MS)
- Accurate Measurement of Isotope Amount Ratios of Lead in Bronze with Multicollector Inductively Coupled Plasma Mass Spectrometry
- Simulation Study to Improve Ion Transmission Efficiency in Mass Spectrometry with a Dual Ion Funnel Ion Source
- more
추천 논문
학술지 홈페이지 이용 환경은 크롬 브라우저 사용을 권장합니다.