A lot of accumulated data of many quantity exist within a institution or an organization, but most data is remained in form of standardization as each institution or organization. There are difficulty in exchange and share of information. New concept of knowledge information resource management to overcome this disadvantage was introduced, and the digitization of knowledge information resources to share and manage accumulated data is been doing. Specially, in science technic or education scholarship it, the tendency that importing XML to process necessary data to exchange and share of knowledge information resources structurally, and limitation of back for search and indexing or reusability is happened according as expression of great many mathematics used inside electron document of these sphere is processed to nonstructural data of image or text and so on. There is interest converged in processing of mathematics that use MathML to overcome this, and we require the solution to be able to process MathML easily and efficiently on structural document. In this paper, designed and implemented of XML document editing system which easy structural process of electronic document for knowledge information resources, and create and express MathML easily on structural document without expert knowledge about MathML.