This study was conducted upon the premise that index terms display the intellectual structure of a specific subject field. In this study, an attempt was made to grasp the intellectual structure of Library and Information Science by clustering the index terms of the journals of the related academic societies at the Library of National Assembly - such as the Journal of the Korean Society for Information Management, the Journal of the Korean Library and Information Science Society, and the Journal of the Korean Society for Library and Information Science. Through the course of the study, index term clusters were generated based on the linkage of the index terms and the frequency of co-occurrence, and moreover, time periods analysis was conducted along with studies on first-appearing terms, in order to clarify the trend and development process of the Library and Information Science. This study also analysed the difference between two intellectual structure by comparing the structure generated by index term clusters with the existing structure of traditional classification systems.