- P-ISSN 2233-4203
- E-ISSN 2093-8950
- 권한신청
- P-ISSN2233-4203
- E-ISSN2093-8950
- ESCI, SCOPUS, KCI
논문 상세
Home > 논문 상세
Elucidating H/D-Exchange Mechanism of Active Hydrogen in Aniline and Benzene-1,2-dithiol
Elucidating H/D-Exchange Mechanism of Active Hydrogen in Aniline and Benzene-1,2-dithiol
Mass Spectrometry Letters / Mass Spectrometry Letters, (P)2233-4203; (E)2093-8950
2021, v.12 no.4, pp.146-151
https://doi.org/10.5478/MSL.2021.12.4.146
(Research Department, Curia, Albany)
(Department of Environment)
(Kyungpook National University)
(Department of Environment)
(Kyungpook National University)
Ahmed,
A.,
Islam,
S.,
&
Kim,
S.
(2021). Elucidating H/D-Exchange Mechanism of Active Hydrogen in Aniline and Benzene-1,2-dithiol. Mass Spectrometry Letters, 12(4), 146-151, https://doi.org/10.5478/MSL.2021.12.4.146
- 다운로드 수
- 조회수
Abstract
In this study, the hydrogen/deuterium (HDX) exchange mechanism of active hydrogen, nitrogen, and sulfur-contain-ing polycyclic aromatic hydrocarbon (PAH) dissolved in toluene and deuterated methanol by atmospheric pressure photoionization (APPI) is investigated. The comparison of the data obtained using APPI suggests that aniline and benzene-1,2-dithiol contain two exchanging hydrogens. The APPI HDX that best explains the experimental findings was investigated with the use of quantum mechanical calculations. The HDX mechanism is composed of a two-step reaction: in the first step, analyte radical ion gets deu-terated, and in the second step, the hydrogen transfer occurs from deuterated analyte to de-deuterated methanol to complete the exchange reaction. The suggested mechanism provides fundamentals for the HDX technique that is important for structural identification with mass spectrometry. This paper is dedicated to Professor Seung Koo Shin for his outstanding contributions in chemistry and mass spectrometry.
- keywords
- atmospheric pressure photoionization (APPI), hydrogen/deuterium exchange (HDX), potential energy surface, quantum mechanical calculation.
- 투고일Submission Date
- 2021-11-13
- 수정일Revised Date
- 2021-12-13
- 게재확정일Accepted Date
- 2021-12-13
권호 내 다른 논문
- Special Issue in Honor of Prof. Seung Koo Shin
- Looking through the Mass-to-Charge Ratio: Past, Present and Future Perspectives
- Integrated Thermochemical Approach to Collision-Induced Dissociation Process of Peptides
- Ion Mobility Signatures of Glutamine-Containing Tryptic Peptides in the Gas Phase
- Elucidating H/D-Exchange Mechanism of Active Hydrogen in Aniline and Benzene-1,2-dithiol
- Li+ and Li+I−Li+ ions Solvated by 1,4-dioxane: An ion Mobility Spectrometry-Mass Spectrometry Study
- Effect of Cation Complexation of Hindered Phenol Antioxidants on their Fragmentation in Electrospray Ionization Tandem Mass Spectrometry
- LC-MS/MS-based Proteomic Analysis to Identify Protein Phosphorylation in Emiliania huxleyi
- Identification of HYIpro-3-1 Metabolites, a Novel Anti-Inflammatory Compound, in Human Liver Microsomes by Quadrupole-Orbitrap High-Resolution Mass Spectrometry
- Fragmentation Analysis of rIAPP Monomer, Dimer, and [M rIAPP + M hIAPP ]5+ Using Collision-Induced Dissociation with Electrospray Ionization Mass Spectrometry
- Separation of Light Rare-Earth Elements Using Gas-Pressurized Extraction Chromatography
- Molecular Characterization of Dissolved Organic Matter Unveils their Complexity, Origin, and Fate in Glacier and Glacial-Fed Streams and Lakes on the Tibetan Plateau
- Development of a Sensitive Analytical Method of Polynemoraline C Using LC-MS/MS and Its Application to a Pharmacokinetic Study in Mice
- more
추천 논문
학술지 홈페이지 이용 환경은 크롬 브라우저 사용을 권장합니다.