- P-ISSN 2233-4203
- E-ISSN 2093-8950
- P-ISSN2233-4203
- E-ISSN2093-8950
- ESCI, SCOPUS, KCI
논문 상세
Home > 논문 상세
Compositional Characterization of Petroleum Heavy Oils Generated from Vacuum Distillation and Catalytic Cracking by Positive-mode APPI FT-ICR Mass Spectrometry
Mass Spectrometry Letters / Mass Spectrometry Letters, (P)2233-4203; (E)2093-8950
2011, v.2 no.2, pp.41-44
https://doi.org/10.5478/MSL.2011.2.2.041
(SK Innovation)
(SK Innovation)
(SK Innovation)
(Kyungpook National University)
(SK Innovation)
(SK Innovation)
(Kyungpook National University)
Kim,
E.,
No,
M.,
Koh,
J.,
&
Kim,
S.
(2011). . Mass Spectrometry Letters, 2(2), 41-44, https://doi.org/10.5478/MSL.2011.2.2.041
- 다운로드 수
- 조회수
Abstract
Molecular compositions of two types of heavy oil were studied using positive atmospheric pressure photoionization(APPI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Vacuum gas oil (VGO) was generated fromvacuum distillation of atmospheric residual oil (AR), and slurry oil (SLO) was generated from catalytic cracking of AR. Theseheavy oils have similar boiling point ranges in the range of 210-650oC, but they showed different mass ranges and double-bondequivalent (DBE) distributions. Using DBE and carbon number distributions, aromatic ring distributions, and the extent of alkylside chains were estimated. In addition to the main aromatic hydrocarbon compounds, those containing sulfur, nitrogen, andoxygen heteroatoms were identified using simple sample preparation and ultra-high mass resolution FT-ICR MS analysis. VGOis primarily composed of mono- and di-aromatic hydrocarbons as well as sulfur-containing hydrocarbons, whereas SLO containedmainly polyaromatic hydrocarbons and sulfur-containing hydrocarbons. Both heavy oils contain polyaromatic nitrogen components. SLO inludes shorter aromatic alkyl side chains than VGO. This study demonstrates that APPI FT-ICR MS is useful formolecular composition characterization of petroleum heavy oils obtained from different refining processes.
- keywords
- Vacuum gas oil, Slurry oil, FT-ICR MS, APPI, Petroleum, Heavy oil.
참고문헌
1
Vendeuvre, C.. (2005). . J. Chromatography A, 1086, 21-.
2
Wang, F. C.. (2004). . J. Sep. Sci, 27, 468-.
3
Garcia, C. L.. (2002). . Anal. Chem, 74, 3849-.
4
Marshall, A. G.. (2002). . Int. J. Mass Spectrom, 215, 59-.
5
Mullins, O. C.. (2005). Asphaltenes, Heavy Oils, and Petroleomics, Chapter 3.
6
Rodgers, R. P.. (2005). . Anal. Chem, 78, 21A-.
7
Purcell, J. M.. (2006). . Anal. Chem, 78, 5906-.
8
Kim, Y. H.. (2010). . J. Am. Soc. Mass Spectrom, 21, 386-.
9
Hur, M. (2010). . Kim. S. Anal. Chem, 82, 211-.
10
Purcell, J. M.. (2007). . Energy & Fuels, 21, 2869-.
11
Bae, E.. (2010). S. Energy &Fuels 2010. Energy &Fuels, 24, 2563-.
12
Mapolelo, M. M. (2010). . Int. J. Mass Spectrom, 300, 149-.
13
Qian, K.. (2008). . Anal. Chem, 80, 849-.
14
Qian, K.. (2007). . G. Energy & Fuels, 21, 2869-.
15
Klein, G. C.. (2006). . Fuel, 85, 2071-.
16
Stanford, L.. (2006). . Energy & Fuels, 20, 1664-.
17
Klein, G. C.. (2006). . Fuel, 85, 2071-.
18
Miyabayashi, K. (2008). . Fuel Processing Technology, 89, 397-.
19
Purcell, J. M.. (2010). . Energy & Fuels, 24, 2257-.
20
McKenna, A. M.. (2009). . Energy & Fuels, 23, 2122-.
21
Qian, K.. (2010). . Anal. Chem, 82, 413-.
22
Pellegrin, V. (1983). . J. Chem. Educ, 60, 626-.
- 투고일Submission Date
- 2011-05-11
- 수정일Revised Date
- 2011-06-07
- 게재확정일Accepted Date
- 2011-06-08
권호 내 다른 논문
- Introduction of Taiwan Society for Mass Spectrometry
- Validation and Applications of Gas Chromatography-Combustion/isotope Ratio Mass Spectrometric Method to Control Misuse of Androgens in Human
- Accurate Quantification of Saccharin Using Isotope Dilution Liquid Chromatography Mass Spectrometry (ID-LC/MS)
- Compositional Characterization of Petroleum Heavy Oils Generated from Vacuum Distillation and Catalytic Cracking by Positive-mode APPI FT-ICR Mass Spectrometry
- Effective Analysis of Dicyclanil in Lamb and Chicken Muscle using HPLCUV/ Vis and LC/MS/MS
- Mass spectrometric studies of competitive binding of C60 and C70 to mesosubstituted porphyrins
- Enrichment of Peptides using Novel C8-functionalized Magnetic Nanoparticles for Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometric Analysis
- Determination of the Uranium Backgrounds in Lexan Films for Single Particle Analysis using FT-TIMS technique
- more
추천 논문
학술지 홈페이지 이용 환경은 크롬 브라우저 사용을 권장합니다.