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Sythesis and Characterization of Transition Metal(II) Complexes with <TEX>$NOTDH_2$</TEX> Schiff Base
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1999, v.12 no.6, pp.498-503
Oh,
J., &
Choi,
Y.
(1999). Sythesis and Characterization of Transition Metal(II) Complexes with <TEX>$NOTDH_2$</TEX> Schiff Base. Analytical Science and Technology, 12(6), 498-503.
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Abstract
Co(II), Ni(II), and Cu(II) complexes with tetradentate schiff base-<TEX>$NOTDH_2$</TEX>, were synthesized. The structures of these complexes were characterized by elemental analysis, IR, UV-visible, NMR spectra, and thermogravimetric analysis. The mole ratio of schiff base(<TEX>$NOTDH_2$</TEX>) to the metal(II) at complexes was found to be 1:1. Cu(II) complexes were four-coordinated configuration, while Co(II) and Ni(II) complexes were hexacoordinated configuration containing two water molecules and all complexes were non-ionic compounds.
- keywords
- schiff base, Bis(2-hydroxy-1-naphthyllidine)-o-toluene-diimine:[<TEX>$NOTDH_2$</TEX>]
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