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Study on analysis of PAHs in consumer products
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2014, v.27 no.4, pp.201-212
https://doi.org/10.5806/AST.2014.27.4.201
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(2014). Study on analysis of PAHs in consumer products. Analytical Science and Technology, 27(4), 201-212, https://doi.org/10.5806/AST.2014.27.4.201
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Abstract
발암성 및 잔류성을 갖는 다환방향족탄화수소(Polycyclic aromatic hydrocarbons, 이하 PAHs)의법적인 규제가 공산품 함유에로 확장된 현황에서, 본 연구에서는 속슬렛 추출에 의한 전처리 및 GC-MS분석에 의한 공산품에 함유된 18종 PAHs의 정량 분석법을 확립하고 공산품 4종에서의 18종 PAHs 함유 여부를 분석하였다. GC-MS SIM 크로마토그램의 머무름 시간 및 피크 면적의 정밀도는 각 0.00%~0.05%및 1.16%~3.69%의 RSD로 측정되었고 각 PAH의 농도 범위 0.3125 mg/L~5.00 mg/L에서 얻은 검정곡선은 상관계수 R2값이 18종 모두 0.999 이상으로 산출되었다. 본 검정곡선을 이용한 18 종 PAHs의 GCMS기기분석의 정량 한계는 0.327 mg/L (Benzo[ghi]perylene)~0.464 mg/L (Acenaphthylene)로 산출되었다. 스파이킹에 의한 18종 PAHs의 속슬렛 추출에 의한 회수율은 DCM, 헥세인, 혹은 톨루엔 사용 시 모두95%~105%로 측정되었고, 이상의 조건에서 국내에서 유통되는 공산품 4종에서 18종 PAHs를 분석한 결과, 3개 시료에서는 Phenanthrene이 정량한계 근방의 소량으로 검출되었고, 망치(손잡이 부분) 시료에서는 Phenanthrene을 비롯한 15종 PAHs가 최대 83.4 mg/kg~최소 8.5 mg/kg 범위로 검출되었다.
- keywords
- polycyclic aromatic hydrocarbons, GC-MS analysis, plastics, grip, consumer products
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