- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
Simultaneous detection of five biocides in household products by gas chromatography-mass spectrometry
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2022, v.35 no.5, pp.197-204
https://doi.org/10.5806/AST.2022.35.5.197
(Department of Environmental Science, Kongju National University)
(Daejeon-Sejong Division, Occupatioanl Safety and Health Agency)
(Department of Environmental Education, Kongju National University)
(Daejeon-Sejong Division, Occupatioanl Safety and Health Agency)
(Department of Environmental Education, Kongju National University)
Kyeong-yun,,
C.
, Hyun-Hee,
L.
, &
Ho-Sang,
S.
(2022). Simultaneous detection of five biocides in household products by gas chromatography-mass spectrometry. Analytical Science and Technology, 35(5), 197-204, https://doi.org/10.5806/AST.2022.35.5.197
- Downloaded
- Viewed
Abstract
A gas chromatography-mass spectrometric method was developed for determining 5-chloro-2-methyl- 4-isothiazolin-3-one (CMIT), 2-methyl-4-isothiazolin-3-one (MIT), 1,2-benzisothiazolin-3-one (BIT), 3-iodo-2- propynyl butyl carbamic acid (IPBC) and benzoic acid (BA) in household products. A 0.5 g sample was placed in a test tube and dissolved with 5 mL water, 5 mL methylene chloride and 1.0 mL methanol. The solution was extracted by ultra-sonication followed by mechanical shaking using the salting out effect. Under the established condition, the lowest quantification limits of all analytes were in the range of 0.04-10 mg/kg and their relative standard deviations were less than 8.0 %. The method was used to analyze 10 household products. As a result of analyzing 10 household products, MIT was detected in the range of 1.2-3.5 mg/kg in 3 of 10 samples, CMIT was detected in the range of 2.6-8.2 mg/kg in 3 of 10 samples, and BA was detected in the range of 5.0-15 mg/kg in 4 of 10 samples. Meanwhile, BIT and IPBC were not detected in any of the products. It has been shown that this method can be used for the simultaneous determination of biocides with various physical and chemical properties in household products.
- keywords
- biocides, household products, ultra-sonication, gas chromatography-mass spectrometry
Reference
1
1. EUR-Lex, https://eur-lex.europa.eu/eli/dir/1998/8/oj/, Assessed 24 Feb 2022.
2
2. K. Taubert, S. Kraus and B. Schulze, Sulfur Rep., 23(1), 79-121 (2002).
3
3. L. Chen and J. C.-W. Lam, J. Environ. Sci., 61, 68-79(2017).
4
4. O. Aerts, A. Goossens, J. Lambert and J.-P. Lepoittevin, Eur. J. Dermatol., 27(2), 115-122 (2017).
5
5. US EPA, https://archive.epa.gov/pesticides/reregistration/web/html/index-150.html/, Assessed 24 Feb 2022.
6
6. WHO, https://www.who.int/ipcs/publications/cicad/cicad26_rev_1.pdf/, Assessed 24 Feb 2022.
7
7. R. Urwin, K. Warburton, M. Carder, S. Turner, R. Agius and S. M. Wilkinson, Contact Dermatitis, 72(6), 381-386 (2015).
8
8. EUR-Lex, https://eur-lex.europa.eu/eli/reg/2017/1224/oj/, Assessed 24 Feb 2022.
9
9. M. C. Goodier, P. D. Siegel, L.-Y. Zang and E. M. Warshaw, Dermatitis, 29(6), 332-338 (2018).
10
10. H. Nakashima, I. Matsunaga, N. Miyano and M. Kitagawa, J. Health Sci., 46(6), 447-457 (2000).
11
11. J. J. Heo, U.-J. Kim and J.-E. Oh, Environ. Eng. Res., 24(1), 137-143 (2019).
12
12. G. Alvarez-Rivera, T. Dagnac, M. Lores, C. Garcia-Jares, L. Sanchez-Prado, J. P. Lamas and M. Llompart, J. Chromatogr. A, 1270, 41-50 (2012).
13
13. E. Garcia-Hidalgo, V. Sottas, N. von Goetz, U. Hauri, C. Bogdal and K. Hungerbühler, Contact Dermatitis, 76(2), 96-106 (2016)
14
14. Q.-B. Lin, T.-J. Wang, H. Song and B. Li, Food Addit. Contam. Part A., 27(12), 1775-1781 (2010).
15
15. T. Wu, C. Wang, X. Wang and Q. Ma, Int. J. Cosmet. Sci., 30(5), 367–372 (2008).
16
16. M. Rosero-Moreano, E. Canellas and C. Nerín, J. Sep. Sci., 37(3), 272-280 (2014).
17
17. I. Baranowska, I. Wojciechowska, N. Solarz and E. Krutysza, J. Chromatogr. Sci., 52(1), 88-94 (2014).
18
18. N.-R. Cha, J.-K. Lee, H.-J. Jeong, J.-C. Cho, M.-J. Kim and S.-Y. Lee, Anal. Lett., 45(15), 2148-2160 (2012).
19
19. H. Zhong, Z. Li, S. Chen, Y. Zeng, J. Zheng, Y. Zeng and D. Li, Molecules, 24(21), 3894 (2019)
20
20. J. B. Wittenberg, B. J. Canas, W. Zhou, P. G. Wang, D. Rua and A. J. Krynitsky, J. Sep. Sci., 38(17), 2983-2988 (2015).
21
21. The Korean Ministry of Environment, Regulations on standards and methods for the analysis of household chemical products subject to safety confirmation, https://www.law.go.kr/, Assessed 24 Feb 2022.
Other articles from this issue
- Problem-solving approach for salbutamol analysis by HPLC during pharmaceutical assay
- Simultaneous detection of five biocides in household products by gas chromatography-mass spectrometry
- Development of analytical method for the isotope purity of pure D2 gas using high-precision magnetic sector mass spectrometer
- Analytical characterization of O3 samples prepared for investigation of tropospheric heterogeneous reactions
- A new merging-zone flow injection system for the quantification of ferrous and ferric ions in aqueous solution and sludge of wastewater
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.