- P-ISSN 1225-0163
- E-ISSN 2288-8985
- Log In/Sign Up
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
Synthesis and Structural Analysis of Binary Alloy (<TEX>$MoRu_3$</TEX>, <TEX>$MoRh_3$</TEX>)
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1998, v.11 no.3, pp.189-193
Park,
Y. J., Lee,
J., Kim,
J. G., Kim,
J. S., &
Jee,
K.
(1998). Synthesis and Structural Analysis of Binary Alloy (<TEX>$MoRu_3$</TEX>, <TEX>$MoRh_3$</TEX>). Analytical Science and Technology, 11(3), 189-193.
- Downloaded
- Viewed
Abstract
Binary alloys, <TEX>$MoRu_3$</TEX> and <TEX>$MoRh_3$</TEX>, have been prepared using arc melting furnace. Mo and the noble metals Ru and Rh are the constituents of metallic insoluble residues, which were found in the early days of the post-irradiation studies on uranium oxide fuels. Detailed structural informations about these alloys have not been reported on JCPDS files of ICDD (International Centre for Diffraction Data). The results of X-ray diffraction study showed that the alloy was crystallized in hexagonal close-packing, well known as <TEX>${\varepsilon}$</TEX>-phase. The X-ray diffraction patterns of these alloys matched well to that of <TEX>$WRh_3$</TEX> with <TEX>$P6_3/mmc$</TEX> of space group. The lattice parameters, a and c, were calculated using the least squares extrapolation. It was found from X-ray photoelectron spectroscopic measurements that Mo on the surface of the alloy was oxidized to Mo(6+), which could be removed by sputtering with Ar ions for approximately 15 minutes. The changes in binding energy of Mo, Ru, and Rh on the surface of the alloy were not observed. Magnetic susceptibility measurements resulted in the typical Pauli-paramagnetic behavior in the temperature range of 2 to 300 K.
- keywords
- Alloy, Insoluble residue, X-ray diffraction, X-ray photoelectron spectroscopy, Magnetic susceplibility
- Downloaded
- Viewed
- 0KCI Citations
- 0WOS Citations
Other articles from this issue
- Electrochemical Studies on the Methylviologen-Sodium Dodecyl Sulfate Solution in the Presence of <TEX>$MgCl_2$</TEX>
- Structural and Thermal Characteristics of Synthesized SiC by Carbothermal Reaction and Sol-gel Method
- Determination of Haloperidol Serum Levels in Psychiatric Patients with Gas Chromatography-Nitrogen Phosphorus Detection
- Development of Analytical Techniques for Human Serum and Urine by Using Glow Discharge
- Adsorption and Preconcentration of Some Heavy Metals by Resorcinol-Formaldehyde Resin
- Retention Behavior and Separation of Phenol Derivatives through Cyclodextrin Complexes in Reversed-Phase Liquid Chromatography
- Synthesis and Structural Analysis of Binary Alloy (<TEX>$MoRu_3$</TEX>, <TEX>$MoRh_3$</TEX>)
- A Study on the Emission of Hazardous Volatile Compounds in Wood and Steel Furniture
- Local Structure Study of Ni in Ni-Zn Alloy Coating on Steel by X-ray Absorption Spectroscopy
- Survey and Control of The Occurrence of Mycotoxins from Postharvest Vegetables in Korea (II) Detection of Major Mycotoxins from Diseased Spice Vegetables (Onions, Garlics and Peppers)
- Analysis of Inorganic Acids by Capillary Zone Electrophoresis
- The Analysis of Ethanol Distribution Level in Biological Specimens
- Effect of New Conditions on Acidic Permanganate COD
- Forensic Analysis of Explosives (II)
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.