- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
Synthesis and Properties of Polydentate Schiff Base Ligands having <TEX>$N_nO_2$</TEX> (n
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1998, v.11 no.5, pp.366-373
Kim,
S., Shin,
Y., &
Park,
S.
(1998). Synthesis and Properties of Polydentate Schiff Base Ligands having <TEX>$N_nO_2$</TEX> (n. Analytical Science and Technology, 11(5), 366-373.
- Downloaded
- Viewed
Abstract
Polydentate Schiff base ligands, BSDT(1,9-bis(2-hydroxyphenyl)-2,5,8-triaza-1,8-nonadiene) having <TEX>$N_3O_2$</TEX> atoms, BSTT(1,12-bis(2-hydroxyphenyl)-2,5,8,11-tetraaza-1,11-dodecadiene) having <TEX>$N_4O_2$</TEX> atoms, BSTP(1,15-bis(2-hydroxyphenyl)-2,5,8,11,14-pentaaza-1,14-pentadodecadiene) having <TEX>$N_5O_2$</TEX> atoms were synthesized. Protonation constants of these polydentate ligands were measured by potentiometry. Stability constants of the complexes between these ligands and the metal ions such as Cu(II), Ni(II) and Zn(II) were measured in DMSO by a polarographic method. It was observed that all metal(II) ions employed in this study formed 1:1 complexes with Schiff base ligands. Stability constants for the complex formation were in the order of Cu(II)>Ni(II)>Zn(II), and for the ligands were in the order of BSTP>BSTT>BSDT. There are due to the increase in the number of donor atoms. Both enthalpy and entropy changes were obtained in negative values. Exothermicity for the complex formation indicated tight binding between the ligands and metal ions. The negative entropy change would be related to the fact that solvent molecules are strongly interacting with the metal complexes.
- keywords
- schiff base ligand, protonation constant, stability constant
- Downloaded
- Viewed
- 0KCI Citations
- 0WOS Citations
Other articles from this issue
- REVIEW : FOR THE IMPROVEMENT AND INVENTORY OF QUALITY CONTROL ON THE ANALYSIS AND MEASUREMENT OF WATER QUALITY POLLUTANT
- A Study on the Separation and Extraction of Polycyclic Aromatic Hydrocarbons in Water Sample by Gas Chromatography/Mass Spectrometry
- Analysis of Tridentate Schiff Base Ni(II) Complex
- Synthesis and Analytical Application of Copper(II) Complex of 2-Pyridinecarboxaldehyde Thiocarbohydrazone
- Studies on the Anodic Oxidation Behavior of Methanol and L-Ascorbic Acid by Using Glassy Carbon Electrodes Modified with Inorganic-Metal Polymeric Films
- Changes of Endogenous Steroids Profile After Oral Administration of Danazol
- Structural and Electrical Characterization of <TEX>$LiMn_2O_4$</TEX> Synthesized by Solid State Reaction
- Synthesis and Properties of Polydentate Schiff Base Ligands having <TEX>$N_nO_2$</TEX> (n
- Simultaneous Determination of Urinary Phytoestrogens and Estrogens by Gas Chromatography/Mass spectrometry
- A New Analytical Method for the <TEX>$Dy^{3+}$</TEX> Ion Using the Luminescence Enhancement by the Treatment of o-Phenanthroline on the TLC Plate
- Chemical Composition and Leaching Characteristic of Coal Fly Ash
- Determination of Germanium (IV) Content in the Korean Medicinal Herbs by Adsorption Stripping Voltammetry
- Separation of 20(R&S) Prosapogenin Isomers of Ginsenoside-<TEX>$Rg_2$</TEX> and -<TEX>$Rg_3$</TEX> from Ginseng Saponins by Reversed-Phase High Performance Liquid Chromatography
- Determination of Eu(III) by Fluorescence Spectrometry using Fiber Optic Sensor
- For the Improvement and Inventory of Quality Control on the Analysis and measurement of Water Quality Pollutant
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.