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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

<TEX>$^{51}V$</TEX> NMR and Cyclic Voltammetry Studies on the Interaction of Vanadate and N-Benzyliminodiacetate in Aqueous Solution

Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1999, v.12 no.3, pp.184-189
Park, Chul-Jin
Park, Sam-Su
Lee, Man-Ho
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Abstract

<TEX>$^{51}V$</TEX> NMR and cyclic voltammetry studies on the interaction of vanadate and N-benzyliminodiacetate (Bz-IDA) in aqueous solution have been studied. From the NMR spectra two <TEX>$^{51}V$</TEX> NMR peaks resulting at -515.5 and -500.1 ppm, due to the complexations between vanadate(V) and Bz-IDA at pH 5. has been observed. From the cyclic voltammograms the reduction-oxidation of the vanadate(V) complex has been found to be one-electron reaction.

keywords
vanadate, N-bengyliminodiacetate, <TEX>$^{51}V$</TEX> NMR


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