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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

Chemical Factors on the Homogeneous Precipitation of Barium Titanyl Oxalate by Dimethyl Oxalate and Their Effects on the Charateristics of Barium Titanate

Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1999, v.12 no.3, pp.230-234
Ryu, Kyoungyoul
Huh, Wooyoung
Lee, Chul
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Abstract

Barium titanyl oxalates (BTO) has been homogeneously prepared by thermal decomposition of dimethyl oxalate (DMO) in hydrochloric solution containing <TEX>$Ba^{2+}$</TEX> and <TEX>$Ti^{4+}$</TEX>. Particles of BTO settled on the bottom of the beaker were collected at the aging time of 120 min using hydroxy propyl cellulose (HPC) as a dispersant. The reaction temperature, the concentration ratio of <TEX>$[DMO]_0/([Ba^{2+}]_0+[Ti^{4+}]_0)$</TEX> and the existence of HPC were found to influence on morphologies of BTO, chemical yields and characteristics of barium titanates formed from their precursors.

keywords
barium titanyl oxalate, homogeneous precipitation, dimethyl oxalate, aqueous hydrochloric acid system


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