Synthesis and Structural Characterization of the One-Dimensional Cadmium(II) Complex with Thiocyanate and 4-Methylimidazole Ligands

Moon, Hyoung-Sil; 문형실; Kim, Chong-Hyeak; 김종혁; Lee, Sueg-Geun; 이석근

P-ISSN1225-0163
E-ISSN2288-8985
SCOPUS, ESCI, KCI

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P-ISSN 1225-0163
E-ISSN 2288-8985

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14권 6호

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티오시아네이트 및 4-메틸이미다졸 리간드로 구성된 1차원 카드뮴(II) 착물의 합성과 구조 분석

Synthesis and Structural Characterization of the One-Dimensional Cadmium(II) Complex with Thiocyanate and 4-Methylimidazole Ligands

분석과학 / Analytical Science and Technology, (P)1225-0163; (E)2288-8985

2001, v.14 no.6, pp.535-539

문형실
김종혁
이석근

문형실, 김종혁, & 이석근. (2001). 티오시아네이트 및 4-메틸이미다졸 리간드로 구성된 1차원 카드뮴(II) 착물의 합성과 구조 분석. , 14(6), 535-539.

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Abstract

One-dimensional coordination polymer of cadmium(II) complex, <TEX>$[Cd(SCN)_2(C_4H_6N_2]_n$</TEX>, has been prepared and characterized by X-ray single crystallography. Structure analysis reveals that each cadmium(II) atom is six-coordinated in distorted octahedral fashion with <TEX>$CdS_2N_4$</TEX> composition. <TEX>$CdS_2N_4$</TEX> composition contains two S and two N atoms from four thiocyanates and tow N atoms from two 4-methylimidazole ligands. Central cadmium(II) atoms are run in parallel to the a-axis and are doubly bridged with neighboring cadmium(II) atoms by the thiocyanate and isothiocyanate ligands. Thus, this complex has a one-dimensional polymer structure in which the 4-methylimidazole is in the trans conformation.

keywords: cadmium complex, thiocyanate, 4-methylimidazole, polymeric 1D structure

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논문 상세

티오시아네이트 및 4-메틸이미다졸 리간드로 구성된 1차원 카드뮴(II) 착물의 합성과 구조 분석

Synthesis and Structural Characterization of the One-Dimensional Cadmium(II) Complex with Thiocyanate and 4-Methylimidazole Ligands

Abstract

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