- P-ISSN 1225-0163
- E-ISSN 2288-8985
- Apply for Authority
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
Rapid analytical method of the polychlorinated biphenyls in PCBs containing liquid wastes
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2008, v.21 no.3, pp.174-182
&
(2008). Rapid analytical method of the polychlorinated biphenyls in PCBs containing liquid wastes. Analytical Science and Technology, 21(3), 174-182.
- Downloaded
- Viewed
Abstract
본 연구에서는 PCBs 함유 폐기물의 적정관리방안을 마련하기 위하여 우리나라의 폐기물공정시 험방법에서 제시하고 있는 액상폐기물 중 PCBs 분석방법을 토대로 시간 및 비용을 효과적으로 보다 신 속하게 분석하는 방법을 제시하고자, 추출 및 전처리방법, 칼럼정제방법, 분석용 칼럼 조건, 기기분석 조 건 및 정량방법을 개발하였다. 분석방법을 검토한 결과 분석시간을 폐기물공정시험방법의 분석시간의 2/ 3정도로 단축시켰고, 검출한계는 0.5 mg/L이었다. 또한, 제안된 신속분석방법을 PCBs 함유 절연유에 적 용하였을 경우 규제기준(2.0 mg/L) 부근인 2.35 mg/L에서 과소평가되는 경향이 나타났으며, 이 시험법을 사용하였을 때 PCBs 함유 폐기물의 부적정하게 평가되는 것을 막기 위해 적용 농도범위를 소수첫째자 리에서 반올림하여 최소자리수를 일의자리 즉 1 mg/L 이하인 경우(0.5~1.4 mg/L)로 제한하는 것이 바람 직한 것으로 나타났다.
- keywords
- rapid method, PCBs containing waste, liquid waste, GC/ECD
Reference
1
1. “Toxic Substance Control Act Inventory”, USA, 1991.
2
2. WHO, “Environmental Health Criteria 140, PCBs”,1993.
3
3. M. D. Erickon, “Analytical Chemistry of PCBs”,Lewis Publishers, New York, 1997.
4
4. V. den Berg, M. Birnbaum and A. Bosabel, Environmental Health Perspectives, 106(12), 775-792(1998).
5
5. G. M. Frame, J. W. Cochran and S. S. Boewadt, Journal of High Resolution Chromatography, 19, 657-668(1996).
6
6. UNEP Chemical, “PCB Transformers and Capacitors, From Management to Reclassification and Disposal”,2002.
7
7. UNEP Chemical, “Regionally based assessment of persistent toxic substances” Regional Report (http://www. chem.unep.ch/pts/), 2002.
8
8. UNEP Chemicals, “Guidelines for the identification of PCBs and materials Containing PCBs”, First Issue,UNEP, 1999.
9
9. UNEP Chemicals, “Survey of urrently Available Non-Incineration PCB Destruction Technologies”, UNEP,2000.
10
10. Basel Convention, “Preparation of a National Environmentally Sound Management Plan for PCBs and PCBComtaminated Equipement”, UNEP, 2003.
11
11. Basel Convention, “Destruction and Decontamination Technologies for PCBs and Other POPs Wastes Under the Basel Convention”, Volumn A, UNEP, 2001.
12
12. 환경부, 폐기물공정시험방법, 2004.
13
13. 국립환경연구원, “폴리염화비페닐류(PCBs) 함유 폐기물의 적정관리방안에 관한 연구”, 2003.
14
14. 국립환경연구원, “절연유 중 PCBs 세부분석지침”,2004.
15
15. 産業廢棄物處理事業振興財, “PCB處理技術ガイドブック”, 1999.
16
16. DIN EN 61619, “Insulation liquids-Contamination by polychlorinated biphenyls (PCBs)-Method determina-tion by capillary column gas chromatography”, 1997.
17
17. Canada EPS1/RM/31, “Reference Method for the Analysis of PCBs”, 1998.
18
18. Alvia Gaskill, Jr., “Effect of Transformer Oil And Petroleum Hydrocarbons As Interferences In Field Screening for PCB Contamination In Soil”.
19
19. “L2000DX User's Manual”, Version 1.24 Rev 4, (http://www.dexsil.com) 2006.
Other articles from this issue
- It's effects for engine emission of water/oil emulsified fuel
- The removal characteristics of PCB by catalyzed fabric filter
- Rapid analytical method of the polychlorinated biphenyls in PCBs containing liquid wastes
- The survey of exposure level for PFOS and PFOA in human plasma from several residential areas in Korea
- Determination of acidic pharmaceuticals in aquatic environmental samples by LC/ESI-MS/MS
- Determination of byproducts after treatment in PCBs-containing transformer oils
- Study on fatty acids composition by latent fingerprint deposition
- Developing of latent fingerprint on human skin
- Preparation and photocatalytic effect of MWCNT/TiO2 composites
- Preparation of ZnO@TiO2 nano coreshell structure by the polymerized complex and sol-gel method
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.