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Adsorption of uranium(Ⅵ), calcium(Ⅱ), and samarium(Ⅲ) ions on synthetic resin adsorbent with styrene hazardous materials
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2009, v.22 no.1, pp.92-100
(2009). Adsorption of uranium(Ⅵ), calcium(Ⅱ), and samarium(Ⅲ) ions on synthetic resin adsorbent with styrene hazardous materials. Analytical Science and Technology, 22(1), 92-100.
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Abstract
초록 1%, 2%, 5% 및 10%의 가교도를 가진 스타이렌(제4류 위험물중 제2석유류) 디비닐벤젠 공중합체에 1-aza-12-crown-4 거대고리 리간드를 치환반응으로 결합시켜 수지들을 합성하였다. 이들 수지의 합성은 염소 함량, 원소 분석, 열중량 분석, 비표면적(BET) 그리고 IR-분광법으로 확인하였다. 수지 흡착제에 의한 금속 이온들의 흡착에 미치는 pH, 시간, 수지의 가교도 그리고 용매의 유전상수에 따른 영향들을 조사하였다. 금속 이온들은 pH 3 이상에서 큰 흡착율을 보였으며, 금속 이온들의 흡착 평형은 2시간 정도였다. 한편, 에탄올 용매에서 수지에 대한 금속 이온의 흡착 선택성은 UO₂<SUP>2+</SUP>＞Ca<SUP>2+</SUP>＞Sm<SUP>3+</SUP> 이온이었고, 우라늄 이온의 흡착력은 1%, 2%, 5% 및 10%의 가교도 순으로 감소하였으며, 용매의 유전상수 크기에 반비례하였다
- keywords
- 1-aza-12-crown-4, macrocyclic ligand, crosslinkage, styrene divinylbenzene (DVB)
Reference
1
1. L. F. Lindoy, K. R. Adam, D. S. Bladwine, A. Bashall, M. McPartlin and H. R. Powell, J. Chem. Soc., Dalton Trans., 237-246(1994).
2
2. M. A. Ahearn, J. Kim, A. J. Leong, L. F. Lindoy, G. V. Meehan and O. A. Mattews, J. Chem. Soc., Dalton Trans., 3591-3599(1996).
3
3. P. G. Grimslery, L. F. Lindoy, H. C. Lip, R. J. Smith and J. T. Baker, Aust. J. Chem., 30, 2095-2100(1977).
4
4. J. Kim. T. H. Ahn, M. R. Lee, M. H. Cho and S. J. Kim, J. Kor. Chem. Soc., 43(2), 167-171(1999).
5
5. K. W. Chi, Y. S. Ahn, K. T. Shim, H. Huh and J. S. Ahn, Bull. Kor. Chem. Soc., 23(5), 688-694(2002).
6
6. H. K. Frensdorff, J. Am. Chem. Soc., 93(3), 4684-4692 (1971).
7
7. H. C. Lip, L. F. Lindoy, J. H. Rea, R. J. Smith, K. Henrick, M. Mcpartin and P. A. Tasker, Inorg. Chem. 19(11), 3360-3365(1980).
8
8. K. S. Huh and S. G. Sin, J. Korean. Ind. Eng. Chem., 9(5), 680-687(1998).
9
9. Y. J. Park, K. K. Park, M. Y. Suh, S. K. Yoon, K. S. Choi, K. Y. Jee and W. H. Kim, J. Kor. Chem. Soc., 44(4), 305-311(2000).
10
10. J. S. Lee and B. S. Choi, Analy. Sci & Tech., 21(4), 272-278(2008).
11
11. G. Bombieri and G. Depaoli, Inorg. Chem. Acta., 18, 123-129(1976).
12
12. T. Hayashita, J. H. Lee, S. Chem and R. A. Bartsch, Anal. Chem., 63(17), 1844-1851(1991).
13
13. E. Blasius and K. P. Janzen, Pure & Appl. Chem., 54, 2115-2122(1982).
14
14. E. Blasius and P. G. Maurer, Makromol. Chem., 178, 649-657(1977).
15
15. H. Otsuka, H. Najima, M. Takagi and K. Ueno, Anal. Chim. Acta, 147, 227-233(1983).
16
16. H. B. Yang, J. G. Lim, E. H. Lee and J. H. Yoo, J. Korean. Ind. Eng. Chem., 10(1), 143-147(1999).
17
17. H. Egawa, T. Nonaka and M. Ikari, J. Appl. Poly. Sci., 29, 2045-2053(1984).
18
18. S. K. Park and J. T. Kim, J. Korean. Ind. Eng. Chem., 13(8), 765-771(2002).
19
19. S. H. Lee, K. R. Kim, J. S. Shon, J. H. Yoo and H. S. Chung, J. Ind. Eng. Chem., 5(4), 296-301(1999).
20
20. J. G. Oh, J. Kor. Chem. Soc., 48(2), 215-219(2004).
21
21. K. B. Chung, H. H. Kim and S. H. Chang, J. Ind. Eng. Chem., 6(1), 8-12 (2000).
22
22. S. M. Howdle, K. Jerabek, V. Leocorbo, P. C. Marr and D. C. Sherrington, Polymer, 41, 7272-7279 (2000).
23
23. M. Y. Suh, T. Y. Eom, I. S. Suh and S. J. Kim, Bull. Kor. Chem. Soc., 8(5), 366-371 (1987).
24
24. Y. Marcus, “Introduction to liquid state chemistry”, John Wiley & Sons, London, (1977).
25
25. C. J. Pederson, J. Am. Chem. Soc., 92(2), 386-391 (1970).
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