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  • P-ISSN1225-0163
  • E-ISSN2288-8985
  • SCOPUS, ESCI, KCI

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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

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학용품 중 프탈레이트류 함유특성 연구

Contents character of phthalates in school supplies

분석과학 / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2012, v.25 no.1, pp.69-75
https://doi.org/10.5806/AST.2012.25.1.069
김교근 (청주대학교)
김교근. (2012). 학용품 중 프탈레이트류 함유특성 연구. 분석과학, 25(1), 69-75, https://doi.org/10.5806/AST.2012.25.1.069
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초록

본 연구에서는 학교 주변 문방구에서 쉽게 구입할 수 있는문규류 4개 제품군(연필, 지우개, 노트,색종이) 22종의 학용품을 조사대상 시료로 선정하여 환경보건법의 환경유해인자로서 관리되고 있는 프탈레이트 8종의 함유특성을 파악하였다. 본 연구결과 조사대상 8종의 프탈레이트류 중 Benzyl butyl phthalate (BBP), Di-n-octyl phthalate (DNOP) 및 Diisodecyl phthalate (DIDP)는 모든 시료에서 검출한계 미만(불검출)으로 나타나 문구류에서는 사용하고 있지 않는 것으로 나타났다. A군의 경우에는 일부 시료에서 Di(2-ethylhexyl) phthalate (DEHP) 및 Diisononyl phthalate (DINP)가 22%~28% 검출되었으며, A-1, A-3 및 A-4의 시료에서는 DINP가 각각 28%, 24% 및 28% 검출되었으며, B군은 조사대상 시료 6건 모두규제농도인 1,000 ppm 이하로 검출되었다. 또한, C-2 시료에서 Dibutyl phthalate (DBP)가 1% 검출되었으며, C-1 및 C-6 시료에서 DEHP가 0.3% 정도 검출되었으며, D-3 시료에서 Di(2-ethylhexyl) adipate (DEHA)가 0.1% 수준으로 검출되었다. 본 연구결과 조사대상 프탈레이트류 중 DINP는 주로 지우개에서만 가장높은 농도로 검출되었으며, 지우개는 저학년일수록 많이 사용하는 학용품으로 피부 접촉을 통해 노출될가능성이 큰 물질인 것으로 판단되었다.

keywords
phthalate, content, dermal exposure, GC/MS

Abstract

This study was performed to survey the school supplies such as pencil, eraser, notebook and color paper. Twenty-two kinds of samples were collected near the school zone, and eight kinds of phthalate which is one of the environmental hazard factors analyzed to estimate the contents characteristics of products. As the results of these research, three kinds of phthalates (BBP, DNOP and DIDP) were not detected in the selected samples. In the A group, DEHP and DINP were detected in the rage of 22%~28%, and DINP was selected 28%, 24% and 28%in the A-1, A-3 and A-4 samples, respectively. But the selected samples in the B group were detected less than 1,000 ppm as regulated level. Also, The DBP was detected 1% in the C-2 sample, and DEHP was detected 0.3%in the C-1 and C-6 samples. The DEHA was detected 0.3% in the D-3 sample. In this study, the DINP was mainly detected the eraser, therefore this kind of phthalate can be exposed through dermal exposure.

keywords
phthalate, content, dermal exposure, GC/MS


참고문헌

1

1. K. Becker, M. Seiwert, J. Angerer, W. Heger, H. M. Koch, R. Nagorka, E. Roβkamp, C. Schluter, B. Seifert and D. Ullrich, International J. of Hygiene and Environ. Health, 207(5), 409-417 (2004).

2

2. G. Latini, Clinica Chimica Acta, 361(1-2), 20-29 (2005).

3

3. http://ec.europa.eu/enterprise/sectors/toys/documents/directives/EU, Toys Safety Directive 88/368/EEC, 1988.

4

4. http://europa.eu/legislation_summaries/consumers/consumerSafety /l32033_en.htm, EU, Directive 2005/ 84/EEC, 2005.

5

5. ‘Standard Consumer Safety Specification for Toy Safety, ASTM F 963’, ASTM International, United States, 2003.

6

6. MoE, Environmental Health Law article 24.

7

7. Kats(Korea agency for technology and standard), Determination of phthalates content in plastic materials, KSM 1991, 2008.

8

8. Kats, Safety guideline of hazardous substance of children's products, Ktas established regulation 2010-0259, 2010.

9

9. MoE, Exposure assessment test method of children's products, NIER established regulation 512, 2010.

10

10. NIER, Establishment of the exposure assessment test method of children's products(I), 2009.

11

11. RIVM report 711701 025, ‘Re-evaluation of human toxicological maximum permissible risk levels’, National Institute for Public Health and the Environment (RIVM), 2005.

12

12. EFSA, ‘Opinion of the Scientific Panel on food additives, flavourings, Processing aids and materials in contact with food (AFC) related to di-Butylphthalate (DBP) for use in food contact materials’, European Federation of Sea Anglers, 2005a.

13

13. US EPA, Integrated Risk Information System(IRIS) (http://cfpub.epa.gov/ncea/iris/index.cfm)

14

14. ‘Phthalate migration from soft PVC toys and child-care articles’, US Scientific Committee on Toxicity, Ecotoxicity and the Environment (CSTEE), 1998.

15

15. EFSA, ‘Opinion of the Scientific Panel on food additives, flavorings, Processing aids and materials in contact with food (AFC) related to di-isodecylphthalate (DIDP) for use in food contact materials’, European Federation of Sea Anglers, 2005b.

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