- P-ISSN 1225-0163
- E-ISSN 2288-8985
- Log In/Sign Up
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
Tandem laser-induced breakdown spectroscopy laser-ablation inductively-coupled plasma mass spectrometry analysis of high-purity alumina powder
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2019, v.32 no.4, pp.121-130
(Department of Chemistry, Mokpo National University)
(Department of Chemistry, Mokpo National University)
(Department of Chemistry, Mokpo National University)
Yonghoon,
L.
, &
Hyang,
K.
(2019). Tandem laser-induced breakdown spectroscopy laser-ablation inductively-coupled plasma mass spectrometry analysis of high-purity alumina powder. Analytical Science and Technology, 32(4), 121-130.
- Downloaded
- Viewed
Abstract
Alumina is one of the most important ceramic materials because of its useful physical and chemical properties. Recently, high-purity alumina has been used in various industrial fields. This leads to increasing demand for reliable elemental analysis of impurities in alumina samples. However, the chemical inertness of alumina makes the sample preparation for conventional elemental analysis a tremendously difficult task. Herein, we demonstrated the feasibility of laser ablation for effective sampling of alumina powder. Laser ablation performs sampling rapidly without any chemical reagents and also allows simultaneous optical emission spectroscopy and mass spectrometry analyses. For six alumina samples including certified reference materials and commercial products, laser-induced breakdown spectroscopy (LIBS) and laser-ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) analyses were performed simultaneously based on a common laser ablation sampling. LIBS was found to be useful to quantify alkali and alkaline earth metals with limits-ofdetection (LODs) around 1 ppm. LA-ICP-MS could quantify transition metals such as Ti, Cu, Zn, and Zr with LODs in the range from a few tens to hundreds ppb.
- keywords
- Alumina, Laser ablation, LIBS, LA-ICP-MS
Reference
1
1. P. Atkins and L. Jones, ‘Chemical Principles The Quest for Insight’, W. H. Freeman and Company, New York, 2008.
2
2. Y. L. Wu, J. Hong, D. Peterson, J. Zhou, T. S. Cho, and D. N. Ruzic, Surf. Coat. Technol., 237, 369-378 (2013).
3
3. G. Molnár, J. Borossay, Z. B. Varga, M. Ballók, and A. Bartha, Mikrochim. Acta, 134, 193-197 (2000).
4
4. H. Matusiewicz, Mikrochim. Acta, 111, 71-82 (1993).
5
5. M. T. Larrea, I. Gómez-pinilla, and A. C. Fariňas, J. Anal. At. Spectrom., 12, 1323-1332 (1997).
6
6. H.A. Foner, Anal. Chem., 56, 856-859 (1984).
7
7. S. Jung, S. Kim, and J. Hinrichs, Spectrochim. Acta B, 122, 45-51 (2016).
8
8. N. Jakubowski, T. Prohaska, L. Rottmann, and F. Vanhaecke, J. Anal. At. Spectrom., 26, 693-726 (2011).
9
9. N. Jakubowski, T. Prohaska, F. Vanhaecke, P. H. Roos, and T. Lindemann, J. Anal. At. Spectrom., 26, 727-757 (2011).
10
10. W. Schelles, S. D. Gendt, V. Muller, and R. V. Grieken, Appl. Spectrosc., 49, 939-944 (1995).
11
11. V. Hoffmann, M. Kasik, P. K. Robinson, and C. Venzago, Anal. Bioanal. Chem., 381, 173-188 (2005).
12
12. M. Kasik, C. Venzago, and R. Dorka, J. Anal. At. Spectrom., 18, 603-611 (2003).
13
13. J. C. Woo, N. Jakubowski, and D. Stuewer, J. Anal. At. Spectrom., 8, 881-889 (1993).
14
14. R. E. Russo, X. Mao, J. J. Gonzalez, V. Zorba, and J. Yoo, Anal. Chem., 85, 6162-6177 (2013).
15
15. F. J. Fortes, J. Moros, P. Lucena, L. M. Cabalín, and J. J. Laserna, Anal. Chem., 85, 640-669 (2013).
16
16. D. W. Hahn and N. Omenetto, Appl. Spectrosc., 66, 347-419 (2012).
17
17. N. L. LaHaye, M. C. Phillips, A. M. Duffin, G. C. Eiden, and S. S. Harilal, J. Anal. At. Spectrom., 31, 515-522 (2016).
18
18. A. W. Miziolek, V. Palleschi, and I. Schechter, ‘Laser-Induced Breakdown Spectroscopy (LIBS) Fundamentals and Applications’, Cambridge University Press, Cambridge, 2006.
19
19. S. H. Tan, and G. Horlick, Appl. Spectrosc., 40, 445-460(1986).
20
20. E. Albalat, P. Telouk, V. Balter, T. Fujii, V. P. Bondanese, M.-L. Plissonnier, V. Vlaeminck-Guillem, J. Baccheta, N. Thiam, P. Miossec, F. Zoulim, A. Puisieux, and F. Albarede, J. Anal. At. Spectrom., 31, 1002-1001 (2016).
21
21. S.-H. Nam, H. Chung, J.-J. Kim, and Y.-I. Lee, Bull. Korean Chem. Soc., 29, 2237-2240 (2008).
22
22. J. P. Singh and S. N. Thakur, ‘Laser-Induced Breakdown Spectroscopy’, Elsevier Science, Amsterdam, 2007.
23
23. NIST Atomic Spectra Database, https://www.nist.gov/pml/atomic-spectra-database.
Other articles from this issue
- Tandem laser-induced breakdown spectroscopy laser-ablation inductively-coupled plasma mass spectrometry analysis of high-purity alumina powder
- Investigation of physical characteristics for Al2O3:C dosimeter using LM-OSL
- An HPLC-UV-based quantitative analytical method for Chrysanthemum morifolium: development, validation, and application
- Simultaneous determination of ampicillin sodium and sulbactam sodium in powder for injection by HPLC
- Application study of PCR additives to improve the split peaks in direct PCR
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.