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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

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    Detection of Al3+ by fluorescent turn-on nitrogen/sulphur-binary doped carbon dots

    Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
    2023, v.36 no.4, pp.161-169
    https://doi.org/10.5806/AST.2023.36.4.161
    Siti Raudhatul Kamali (Department of Environmental Science, University of Mataram)
    Chang-Nan Chen (Department of Applied Chemistry, Chaoyang University of Technology)
    Tai-Huei Wei (Department of Physics, National Chung Cheng University)
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    Abstract

    In this study, a straightforward and precise nitrogen/sulphur-codoped carbon dots (N/S-CD) was produced using a microwave irradiation approach. The N/S-CD was formulated from succinic acid (SA), bis- (3-aminopropyl)-amine (BAPA), and sodium thiosulphate (STS) as sources of carbon, nitrogen, and sulphur, respectively. The synthesized N/S-CD established a valuable quantum yield (QY) of 70 % and was sensitive to aluminium ion (Al3+) with a detection limit of 0.21 μM and a linear concentration range of 0-100 μM. When detecting Al3+ in real water samples, the N/S-CD resulted in a satisfactory recovery in the range of 91.14 %- 103.37 %. Thus, the proposed study is very promising for Al3+ detection in environmental water samples.

    keywords
    carbon dots, microwave, aluminium ion, water samples


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