Studies on the effect of the intermolecular hydrogen bonding on the vibrational frequencies of the acetonitrile under matrix isolation conditions at liquid-<TEX>$N_2$</TEX> temperature
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1994, v.7 no.1, pp.79-89
Ma, Keum Ja
Jeong, Jong Hak
Jeong, Gi Ho
Ma,
K. J., Jeong,
J. H., &
Jeong,
G.
H.
(1994). Studies on the effect of the intermolecular hydrogen bonding on the vibrational frequencies of the acetonitrile under matrix isolation conditions at liquid-<TEX>$N_2$</TEX> temperature. Analytical Science and Technology, 7(1), 79-89.
Abstract
Interactions between the acetonitrile and other organic molecules such as furan, pyrrole, pyrrolidine, thiophene, tetrahydrothiophene and acetaldehyde was studied with the infrared absorption spectroscopy under matrix isolation conditions. Xe was used as a major matrix material. Acetonitrile showed strong interactions with pyrrole and thiophene, and little interactions with pyrrolidine and acetaldehyde.
- keywords
-
FTIR,
acetonitrile,
hydrogen bonding