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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

Characterization of Humic Acid in the Chemical Oxidation Technology(II) - Characteristics by Ozonation -

Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2000, v.13 no.2, pp.241-249
Rhee, Dong Seok
Jung, Young-Rim
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Abstract

In this paper, ozonation of humic acid in water was characterized using <TEX>$UV_{254}$</TEX> absorbance, TOC, Ultra Filtration and <TEX>$^{13}C-NMR$</TEX>. Also, carbonyl compounds in ozonated water were analyzed by GC/MS using PFBOA method. Ozonation by-products of water containing humic acid were determined as formaldehyde, acetaldehyde, acetone, glyoxal and methylglyoxal. Results of <TEX>$UV_{254}$</TEX> absorbance and TOC with ozonation time at humic acid 20, 100ppm represent that decrease rate of 80% within ozonation time is 20 min and TOC removal rate of 40-50% within ozonation time is 30 min. Results for <TEX>$^{13}C-NMR$</TEX> and Ultra Filtration, humic acid of high molecular weight by ozonation are oxidated and decomposed so that it was conversed low molecular weight such as aldehydes, carboxylic acid.

keywords
humic acid, ozonation, PFBOA method


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