• P-ISSN1225-0163
  • E-ISSN2288-8985
  • SCOPUS, ESCI, KCI

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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

Determination of Cadmium(II) Ion Using the Nafion-Ethylenediamine-Modified Glassy Carbon Electrode

Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2001, v.14 no.2, pp.123-130
Kim, Jin Ah
Ko, Young Chun
Park, Chan Ju
Park, Byung Ho
Chung, Keun Ho
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Abstract

Determination of cadmium(II) ion with a perfluorinated sulfonated polymer-ethylenediamine(nafion-en) modified glassy carbon electrode was studied. It was based on the chemical reactivity of an immobilized layer(nafion-en) to yield complex <TEX>$[Cd(en)_2]^{2+}$</TEX>. The reduction peak potential by differential pulse voltammetry(DPV) was observed at <TEX>$-0.780({\pm}0.005)V$</TEX> vs. As/AgCl. The linear calibration curve was obtained in cadmium(II) ion concentration range <TEX>$5.0{\times}10^{-7}-2.0{\times}10^{-5}M$</TEX>, and the detection limit(3s) was <TEX>$2.20{\times}10^{-7}M$</TEX>. The detection limit of nafion-en modified glassy carbon electrode has been shown about 14 higher sensitivity than a bare glassy carbon electrode.

keywords
nafion (perfluorinated sulfonated polymer)-ethylenediamine modified glassy carbon electrode, determination of cadmium (II) ion, differential pulse voltarnmetry


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