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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

Studies on the Stability constants of complexes between rare earth elements and ethylenediaminediacetic acid

Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2001, v.14 no.4, pp.371-375
Cha, Ki-Won
Hyun, In-Seong
Choi, Hyun-Chol
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Abstract

The stability constants of complexes between rare earth elements(Yb, Dy, Sm, Nd, Pr, Ce, La) and ethylenediaminediacetic acid(EDDA) have been measured for the separation of rare earth elements by potentiometric method. The <TEX>$pk_1s$</TEX> of <TEX>$MA^+$</TEX> complexes are in the range of 8.80-6.72 and the <TEX>$pk_2s$</TEX> of <TEX>$MA_2^-$</TEX> complexes are in the range of 7.43-4.37. The magnitude sequences of the stability constants are the reverse of the ionic size of rare earth elements.

keywords
stability constants, rare earth elements, ethylenediaminedi aceticacid


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