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Inclusion Selectivity of the Cyanocadmate Host Complex with Piperazine Ligand for Aromatic Guest Molecules; Benzene, Toluene, Ethylbenzene and Sylene Isomers
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2003, v.16 no.4, pp.333-338
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(2003). Inclusion Selectivity of the Cyanocadmate Host Complex with Piperazine Ligand for Aromatic Guest Molecules; Benzene, Toluene, Ethylbenzene and Sylene Isomers. Analytical Science and Technology, 16(4), 333-338.
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Abstract
Inclusion selectivity of a three-dimensional piperazine-ligated cyanocadmate host complex, <TEX>$[Cd_x(CN)_{2x}\{HN(CH_2CH_2)_2NH\}_y]{\cdot}zG$</TEX>, has been investigated for benzene (B), toluene (T), ethylbenzene (E), o- (O), m- (M), and p-xylene (P) isomers as the aromatic guest molecules. From the binary, ternary and quarternary guest mixtures of E and xylene isomer (X), the order of inclusion selectivity in the host complex is O>E>P>M. From the binary to quinary BTX mixtures, the order of preference in the complex is seen to be B>T>O<TEX>${\gg}$</TEX>P>M.
- keywords
- inclusion selectivity, cyanocadmate host complex, piperazine ligand, aromatic guest molecules
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