- P-ISSN 1225-0163
- E-ISSN 2288-8985
- Log In/Sign Up
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
Preparation and crystal structure of azido bridged one-dimesnsional polymeric cadmium(Ⅱ) complex, [Cd(N3)2(2-ethylimidazole)2]
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2005, v.18 no.5, pp.391-395
&
(2005). Preparation and crystal structure of azido bridged one-dimesnsional polymeric cadmium(Ⅱ) complex, [Cd(N3)2(2-ethylimidazole)2]. Analytical Science and Technology, 18(5), 391-395.
- Downloaded
- Viewed
Abstract
[Cd(N3)2(2-ethylimidazole)2] 착물을 합성하고 단결정 X-선 회절법으로 구조를 규명하였다. 이 착물은 단사정계, 공간군 Cc, a=16.200(3), b=12.926(3), c= 7.007(1) Å, β = 102.29(3)o, V = 1433.7(5) Å3,Z=4로 결정화되었으며, 1874 개의 독립적인 회절반점에 대한 최종 신뢰도 인자 R1 및 ωR2 값은 각각0.0239 및 0.0604 이었다. Cd(II) 금속 원자는 4개의 azido 리간드와 2개의 2-ethylimidazole 리간드의 질소 원자가 배위되어 약간 찌그러진 팔면체 구조를 나타낸다. c 축 방향으로 배열되어 있는 Cd(II) 금속 원자 사이를 azido 리간드가 end-on (μ-1,1) 형태로 bridge 하고 2-ethylimidazole 리간드가 시스 형태로 결합하여 이 착물은 1차원의 zigzag 사슬 구조를 형성한다.
- keywords
- cadmium complex, azide, 2-ethylimidazole, crystal structure
Reference
1
(1997.) Infrared and Raman Spectra of Inorganicand Coordination Compounds,
Other articles from this issue
- A study on the analysis of rare earth elements by diferential pulse anode stripping voltametry
- Quantitative analysis of silver in chlorinated polymer
- Systhesis, crystal structure, and thermal property of piperazine-templated copper(Ⅱ) sulrate,{H2NCH2CH2NH2CH2CH2} {Cu(H2O)6}(SO4)2
- Structural characterization and thermal behaviour of the bis(2-aminothiazole)bis(isothicyanato)zinc(Ⅱ) complex, Zn(ncs)2(C3H4N2S)2
- Preparation and crystal structure of azido bridged one-dimesnsional polymeric cadmium(Ⅱ) complex, [Cd(N3)2(2-ethylimidazole)2]
- Effedcts and optimum conditions of pre- reductant in the snalysis of inorganic arsenic by hydride geeration-atomic absorption spectrometry
- Pretreatment of Fish for the determination of polycyclic aromatic hydrocarbons using alkali digestion
- Analysis of the polychlorianted biphenyls in transformer oils using peak matching method
- The study of distribution relationship of dioxin isomers in some environmental matrix
- Some considerations for the analytical approaches to measure atmospheric ammonia : tests on a relative performance of a portable colorimeter against UV/VIS spectrophotometer
- Comparison of breathing air samples between smoker and non-smoker by means of aromatic volatile organic compounds(VOC)
- Effects of surface properies and solution ph on the pollutants removal of K-PAC
- The studies on characteristics of the vegetable oils
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.