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Hydro/solvothermal synthesis, crystal structure, and thermal behaviour of piperazine-templated nickel(Ⅱ) and cobalt(Ⅱ)sulfates
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2006, v.19 no.4, pp.309-315
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(2006). Hydro/solvothermal synthesis, crystal structure, and thermal behaviour of piperazine-templated nickel(Ⅱ) and cobalt(Ⅱ)sulfates. Analytical Science and Technology, 19(4), 309-315.
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Abstract
Two piperazine-templated metal sulfate complexes, <TEX>$(C_4N_2H_{12})[Ni(H_2O)_6](SO_4)_2$</TEX>, I and (<TEX>$C_4N_2H_{12}$</TEX>) <TEX>$[Co(H_2O)_6](SO_4)_2$</TEX>, II, have been synthesized by hydro/solvothermal reactions and their crystal structures analyzed by single crystal X-ray diffraction methods. Complex I crystallizes in the monoclinic system, <TEX>$P2_1/n$</TEX> space group, a
- keywords
- Metal(II) sulfate, piperazine, organic template, hydro/solvothermal synthesis, crystal structure, thermal behaviour
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