• P-ISSN1225-0163
  • E-ISSN2288-8985
  • SCOPUS, ESCI, KCI

Article Detail

Home > Article Detail
  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

Separation properties of 209 PCB congeners on capillary columns and identification of PCBs congeners in aroclor standards for source identification

Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2006, v.19 no.4, pp.352-364



  • Downloaded
  • Viewed

Abstract

This study was performed to search for useful separation properties and elution orders of three GC columns (DB-1, DB-5MS, SPB-Octyl) for 209 PCBs congeners using M-1668A-0.01X-SET of the AccuStandard Inc.. In addition, to confirm the quantitative peak in peak pattern method, the IUPAC Nos. of PCBs congener peaks were identified with 4 Aroclor standards (Aroclor-1242, 1248, 1254 and 1260). The separation property of dioxin-like PCBs congeners by four columns (DB-1, DB-5MS, SP-2331 and SPB-Octyl) was excellent in SP-2331. DB-1 and SPB-Octyl columns are necessary to use with a column of other types.

keywords
PCBs, GC column, separation property, Aroclor


Reference

1

McFarland, V.A, (1989) Environ. Health Perspect,

2

여현구, (2002) 대한환경공학회지,

3

국립환경연구원, (2004) 절연유 중 폴리염화비페닐류 (PCBs) 세부분석지침,

4

홍종기, (2004) 한국분석과학회지,

5

김종국, (2002) 한국분석과학회지,

6

Mikael, T.H, (1998) Organohalogen compounds,

7

U.S. EPA,

8

김경수, (2005) 한국분석과학회지,

9

Hirai, Y, (2002) 情報を用いた大中 Dioxin-like PCBの生源にする究,

10

Kobayashi, N, (2004) 東京流域の環境水中におけるダイオキ シン類汚染の態把握とモデルを用いた濃度予測,

11

국립환경과학원, (2005) PCBs 함유 제품 및 폐기물 중의 PCBs 분석방법 개발,

12

U.S. EPA, (1999) Method 1668 Revision A: Chlorinated Biphenyl Congeners in Water, Soil, Sediment, and Tissue by HRGC/HRMS,

13

Vetter, W, (1998) J. Chromatogr. A,

14

Masuzaki, Y, (2003) 제12회 일본 환경 화학토론회 강연요지집, 제12회 일본 환경 화학토론회

15

Frame, G.M, (1996) J. High Res. Chromatogr.,

16

Mimura, K, (1999) 福岡誌,

17

Harju, M.T, (1998) Organohalogen compounds,

상단으로 이동

Analytical Science and Technology