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  • P-ISSN1225-0163
  • E-ISSN2288-8985
  • SCOPUS, ESCI, KCI

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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

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    Determination of copper(Ⅱ) in various samples by flame atomic absorption spedtrophotometry after column separation by adsorption of its N-benzoylphenylhydroxylamine complex on benzophenone

    분석과학 / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
    2007, v.20 no.1, pp.55-60
    최희선 (수원대학교 화학과)
    박문희 (수원대학교 화학과)
    최희선, & 박문희. (2007). . 분석과학, 20(1), 55-60.
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    Abstract

    A sensitive technique for the determination of trace Cu(II) in various samples after the column preconcentration by adsorbing its N-benzoylphenylhydroxylamine (BPHA) onto benzophenone was developed. Several experimental conditions such as the pH of the sample solution, the amount of chelating agent, the amount of benzophenone, and the flowrate of sample solution and so forth were optimized. The interfering effects of diverse concomitant ions were investigated. Fe(III) and <TEX>$CN^-$</TEX> interfered with more seriously than any other ions. However, the interference by these ions could be overcome sufficiently by adjusting the added volume of 0.01M BPHA to 10 mL. The dynamic range, the correlation coefficient (<TEX>$r^2$</TEX>) and the detection limit obtained by this proposed technique were 5.0~120 ng/mL, 0.9974, and 2.1 ng/mL, respectively. For validating this proposed technique, the aqueous samples (stream water, reservoir water, and wastewater), the plastic sample and the diluted brass sample were used. Recovery yields of 93~102% were obtained. These measured data were not different from ICP-MS data at 95% confidence level. This method was also validated by the rice flour CRM (normal, fortified) samples. Based on the results from the experiment, it was found that this proposed technique could be applied to the determination of Cu(II) in various real samples.

    keywords
    preconcentration, N-benzoylphenylhydroxylamine, benzophenone, Copper(II)


    참고문헌

    1

    C. N. Sawyer, (1996) ？Chemistry for Environmental Engineering？, McGraw-Hill, New York, U.S.A.

    2

    Z. Kowalewska, (2005) Spectrochim,

    3

    Welcher, (1973) ？Standard methods of chemical analysis？, Krieger PublishingCo

    4

    D. A. Skoog, (1998) ？Principles of instrumental analysis？,, 13, Saunders College Publishing, Philadelphia, U.S.A.

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