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- E-ISSN 2288-8985
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Determination of trace arsenic in seawater by flow injection-hydride generation inductively coupled plasma mass spectrometry
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2008, v.21 no.4, pp.316-325
(2008). Determination of trace arsenic in seawater by flow injection-hydride generation inductively coupled plasma mass spectrometry. Analytical Science and Technology, 21(4), 316-325.
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Abstract
연속흐름주입-수소화물생성-유도결합플라스마질량분석장치를 사용하여 바닷물시료중의 비소를 분석하였다. 두 종류의 바닷물표준시료인 CASS-4, NASS-5를 사용하여 측정값과 인증값을 비교함으로써 본 분석법의 정확성을 확인하였다. 분석결과 CASS-4의 경우 1.17±0.07 μg/L (인증값 1.11±0.16 μg/L), NASS-5의 경우 1.24±0.08 μg/L (인증값 1.27±0.12 μg/L)의 값을 얻었다. 이는 각각 독립적으로 5회 측 정된 결과의 확장불확도로 표시된 결과이며 CASS-4의 경우 6.2%, NASS-5의 경우 6.8%이었으며 모두 인증값의 불확도 범위안에 있었다. 검량선의 기울기와 바탕값의 표준편차로부터 구한 As+ (m/z=74.9216) 의 검출한계는 0.01 ug/kg이었다. 검량선의 직선성은 매우 양호하였다. (R2=1). DRC gas로 산소기체를 사 용하여 AsO+ (m/z=90.9165)로 검출하는 방법을 사용하여 결과를 비교하였으며 분석감도는 약 25배 정도 감소하였으나, 검량선의 직선성이 매우 잘 나타났으며, 분석결과도 As+ (m/z=74.9216)로 검출할 때와 동 일한 결과를 얻을 수 있었다.
- keywords
- ICP-MS, Flow Injection, Hydride Generation, Arsenic, CASS-4, NASS-5 reference material
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