Article Detail

Home > Article Detail
  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

Synthesis and property analysis of hydropolysilanes for amorphous and polycrystalline silicon

Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2011, v.24 no.2, pp.105-112
https://doi.org/10.5806/AST.2011.24.2.105




  • Downloaded
  • Viewed

Abstract

Syntheses and property analysis of hydropolysilanes were studied. Those hydropolysilanes can be utilized as precursors for amorphous silicon and polycrystallline silicon for the purpose of the solar cell and the thin film transister for the next generation's semiconductors. Most important characteristics of this study are to find optimized conditions for the synthesis and property analysis of soluble hydropolysilanes. Also the possibility of pyrolytic conversion to amorphous and polycrystalline silicon was investigated.

keywords
chloropolysilanes (CPS), hydropolysilanes (HPS), property analysis of hydropolysilanes, amorphous silicon (a-Si), polycrystalline silicon (p-Si)


Reference

1

1. Kim, H. K. and Matyjaszewski, K. J. Am. Chem. Soc., 110, 3321(1988).

2

2. Matyjaszewski, K., Greszta, D., Jeffrey, S. H. and Kim, H. K. Macromolecules, 28, 59(1995).

3

3. Kani, R., Nakano, Y., Yoshida, H., Mikoshiba, S. and Hayase, S. J. Polymer Sci. Pare A. Polym. Chem., 35, 2355(1997).

4

4. Miller, R. D., Thomson, D., Sooriyakumaran, R. and Fickes, G. N. J. Polym. Sci. Part A, Polym. Chem., 29, 813(1991).

5

5. Suzanne, M., Bushnell, W., Michael, J. M., John and H. S. Polymer., 37, 2067(1996).

6

6. Kipping, F. S. J. Chem. Soc., 125, 2291(1924).

7

7. Robert, E. B., Cragg, R. H., Richard, G. J. and Anthony, C. S. Nature, 353, 26 (1991).

8

8. Ajima, S., Hayashi, J. and Omori, M. Chem. Lett., 931 (1975).

9

9. Mazdiyasni, K. S., West, R. and David, L. D, J. Am, Ceram. Soc., 61, 504(1978).

10

10. Trujillo, R. E. J. Organomet. Chem., 198, C27(1980).

11

11. Jung, I. N., Lee, G.-H., Suk, M. Y. and Yeon, S. H. Bull. Korean Chem. Soc., 12, 706(1991).

12

12. Jang, S. H., Park, C. K., Song, Y. S. and Lee, G.-H. Bull. Korean Chem. Soc., 17, 443(1996).

13

13. West, R. Organopolysilanes, in “Comprehensive Organometallic Chemistry”, Vol. 2, 365, ed. by Wilkinson, G., Stone, F. G. A., Abel, E. W., Pergamon, Oxford, 1982.

14

14. West, R. Organopolysilanes, in “Comprehensive Organometallic Chemistry II”, vol. 2, 77, ed. by Abel, E. W., Stone, F. G. A., Wilkinson, G., Pergamon, Oxford, 1995.

15

15. Koe, J. R. Organopolysilanes, in “Comprehensive Organometallic Chemistry III”, vol. 3, 549, ed. by Crabtree, R. H., Mingos, D. M. P., Elsevier Science, Oxford, 2007.

16

16. Koe, J. R. Polymer int., 58, 255(2009).

17

17. John., P., Odeh, I. M., Thomas, M. J. K. and Wilson, J. I. B. J. de Physique, pC4-651(1981).

18

18. Shimoda, T., Miyashita, S., Seki, S., Furusawa, M., Yudasaka, I., Takeuchi, Y. and Matsuki, Y. U. S. Patent 6541354 B1 (2003).

19

19. Shimoda, T., Matsuki, Y., Furusawa, M., Aoki, T., M., Yudasaka, Tanaka, H., Iwasawa, H., Wang, D., Miyasaka, M. and Takeuchi, Y., Nature, 440, 783(2006).

20

20. Shiho, H. and Kato, H., U. S. Patent 0185712 A1(2006).

21

21. Lee, G.-H., West, R. and Muller, T., J. Am. Chem. Soc., 125, 8114(2003).

상단으로 이동

Analytical Science and Technology