- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
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Determination of benzene, toluene, ethylbenzene and o-xylene in bottled waters by headspace solid-phase microextraction and gas chromatography/mass spectrometry
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2011, v.24 no.2, pp.119-126
https://doi.org/10.5806/AST.2011.24.2.119
(2011). Determination of benzene, toluene, ethylbenzene and o-xylene in bottled waters by headspace solid-phase microextraction and gas chromatography/mass spectrometry. Analytical Science and Technology, 24(2), 119-126, https://doi.org/10.5806/AST.2011.24.2.119
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Abstract
The amount of benzene, toluene, ethylbenzene, and o-xylene (BTEX) in 30 kinds of bottled waters purchased from market and 9 kinds of tap waters from home were determined using headspace solid phase microextraction (HS-SPME). The sample was stirred at 1200 RPM G for 4 min using a magnetic bar with 100μm PDMS as adsorbent for BTEX. Then it was desorbed from the fiber for 1 min at room temperature. Quantitation was achieved using standard calibration method. The limit of detection was determined as benzene 0.39 (±0.04)ng/mL, toluene 0.08 (±0.04) ng/mL, ethylbenzene 0.04 (±0.01) ng/mL, and o-xylene 0.05 (±0.02) ng/mL. Benzene and o-xylene were not detected in any samples, but toluene was detected in 11 samples, and ethylbenzene was detected just in 3 samples among 30 investigated bottled waters. The concentration range of investigated materials for toluene and o-xylene were 0.24 (±0.09)~2.95 (±0.08) ng/mL, 0.08 (±0.06)~0.93 (±0.10) ng/mL, respectively.
- keywords
- BTEX, bottled water, tap water, GC/MS, SPME
Reference
1
1. 국립환경연구원, 1997, 먹는물 수질관리기법 개발에 관한 연구 (I).
2
2. World Health Organization, 2008, Guideline for Drink-ing Water Quality(3rd Ed.)
3
3. 한무영, WHO 음용수 수질 가이드라인(1권, 대한상하수도학회 수도연구회), pp. 79-81, 1999.
4
4. http://www.epa.gov/safewater/dwh/c-voc/benzene
5
5. K. Demeestere, J. Dewulf, Bavo De Witte and Herman Van Langenhove, J. Chromatogr. A, 1153(1-2), 130-144(2007).
6
6. Milena Povolo and Giovanna Contarini, J. Chromatogr. A, 985, 117-125(2003).
7
7. Sophie Guillot, Mary T. Kelly, Hlne Fenet and Michel Larroque, J. Chromatogr. A, 1101, 46-52(2006).
8
8. Ralf Eisert and Karsten Levsen, J. Chromatogr. A, 733, 143-157(1996).
9
9. Heather Lord and J. Pawliszyn, J. Chromatogr. A, 885, 153-193(2000).
10
10. J. Pawliszyn, “Applications of solid phase-microextraction”, Department of Chemistry University of Waterloo, Waterloo, RSC CHROMATOGRAPHY MONOGRAPHS, 1999.
11
11. E. E. Stashenko and J.R. martinez, J. of biochemical and biophysical method, 70(2), 235-242(2007)
12
12. S. Y. Park, K. H. Kim, H. S. Yang, J. Y. Ha, K. H.Lee, and J. W. Ahn, Anal Sci. Technol., 21(2), 93-101(2008).
13
13. S. W. Ahn and S. W. Chang, J. Kor. Soc. for Environ. Ana., 7(2), 83-89(2004).
14
14. L. K. Gardner and G. D. Lawrence, J. Agric Food Chem. 40, 693-695(1993).
15
15. J. H. Kim and K. M. Lee, Anal Sci. Technol., 20(3), 237-245(2007).
16
16. T. W. Kang, H. S. Pyo and J. K. Hong, Anal Sci. Technol., 21(4), 259-271(2008).
17
17. D. Louch, S. Moltagh and J. Pawliszyn, Anal. Chem., 64, 1187-1199(1992).
18
18. G. Ouyang, Y. Chen, L. Setkova and J. Pawliszyn, J. Chromatogr. A, 1097, 9-16(2005).
19
19. J. Pawliszyn, TrAC, 14, 113-122(1995).
20
20. T. J. Kim, Anal Sci. Technol., 15(5), 51A-62A(2002).
21
21. M. Povolo and G. Contarini, J. Chromatogr. A, 985, 117-125(2003).
22
22. Z. Zhang and J. Pawliszyn, Anal. Chem., 65, 1843-1852(1993).
23
23. CL. Arthur, Anal. Chem., 62, 2145-2148(1990).
24
24. Z. Zhang, M. J. Yang and J. Pawliszyn, Anal. Chem., 66, 844-853(1994).
25
25. K. F. Pratt and J. Pawliszyn, Anal. Chem, 64, 2101- 2110(1992).
26
26. M. J. Yang and J. Pawliszyn, Anal. Chem, 65, 2538- 2541(1993).
27
27. P. Popp and A. Paschke, Chromatographia, 46(7/8), 419-424(1997).
28
28. Jie Ji, Chunhui Deng, Wenwen Shen and Xiangmin Zhang, Talanta, 69, 894-899(2006).
29
29. O. Ezequerro, B. Pons and M. M. Tena, J. Chromatogra. A, 1035, 17-22(2004).
30
30. O. Ezequerro, B. Pons and M. M. Tena, J. Chromatogra. A, 999, 155-164(2003).
31
31. D. J. Djozan and Y. Assadi, Chromatographia, 45, 183-189(1997).
32
32. Janusz Pawliszyn, “SOLID-PHASE MICROEXTRACTION: Theory and Practice”, Course notes, Department of Chemistry University of Waterloo, April 2004.
33
33. 김강진, 김하석, 이승호, 이원 역, 최신분석화학(4판, 자유아카데미) pp. 112-113, 2009.
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