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Enhanced ion-exchange properties of clinoptilolite to reduce the leaching of nitrate in soil
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2022, v.35 no.2, pp.41-52
https://doi.org/10.5806/AST.2022.35.2.41
(Department of Chemical Engineering, Vaal Universit of Technology, South Africa)
John,
K.
(2022). Enhanced ion-exchange properties of clinoptilolite to reduce the leaching of nitrate in soil. Analytical Science and Technology, 35(2), 41-52, https://doi.org/10.5806/AST.2022.35.2.41
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Abstract
The leaching of nitrate from soil increases the concentration of elements, such as nitrogen, phosphorus, and potassium, in water, causing eutrophication. In this study, the feasibility of using clinoptilolite as an ionexchange material to reduce nitrate leaching in soil was investigated. Soil samples were collected from three soil depths (0 − 30, 30 − 90, and 90 − 120 cm), and their sorption capacity was determined using batch experiments. The effects of contact time, initial concentration, adsorbent dosage, pH, and temperature on the removal of NO3 − were investigated. The results showed that an initial concentration of 25 mg L−1, a contact time of 120 min, an adsorbent dosage of 5.0 g/100 mL, a pH of 3, and a temperature of 30 oC are favorable conditions. The kinetic results corresponded well with a pseudo-second-order rate equation. Intra-particle diffusion also played a significant role in the initial stage of the adsorption process. Thermodynamic studies revealed that the adsorption process is spontaneous, random, and endothermic. The results suggest that a modification of clinoptilolite effectively reduces the leaching of nitrate in soil.
- keywords
- clinoptilolite, ion exchange, leaching, nitrate, soil
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