- P-ISSN 1225-0163
- E-ISSN 2288-8985
- Log In/Sign Up
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
Studies on Electroanalytical Chemistry for the Oxygen Adducted Tetradentate Schiff base Cobalt(III) Complexes in Pyridine Solution
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1995, v.8 no.1, pp.55-62
Rim,
C., Chae,
H., Chjo,
K., &
Choi,
Y.
(1995). Studies on Electroanalytical Chemistry for the Oxygen Adducted Tetradentate Schiff base Cobalt(III) Complexes in Pyridine Solution. Analytical Science and Technology, 8(1), 55-62.
- Downloaded
- Viewed
Abstract
Tetradentate Schiff base cobalt(II) complexes such as <TEX>$Co(II)_2-N$</TEX>, N-bis(salicylidene)-m-phenylendiimine; [<TEX>$Co(II)_2(SMPD)_2(H_2O)_4$</TEX>] and <TEX>$Co(II)_2-N$</TEX>, N-bis(salicylidene)-p-phenylendiimine: [<TEX>$Co(II)_2(SPPD)_2(H_2O)_4$</TEX>], and oxygen adducted cobalt (III) complexes such as [<TEX>$Co(III)_2O_2(SMPD)_2(Py)_2$</TEX>] and [<TEX>$Co(III)_2O_2(SPPD)_2(Py)_2$</TEX>] in pyridine solutions were synthesized. It was identified that the oxygen adducted cobalt(III) complexes have hexacoordinated octahedral configuration with pyridine and oxygen from the measurement of elemental analysis, AA, IR spectra, and TGA. The redox processes were investigated for the oxygen adducted complexes in 0.1M TEAP-pyridine solution, using cyclic voltammetry on the glassy carbon electrode. The redox processes of oxygen adducted Co(III) complexes result in <TEX>$$[Co(III)_2-O_2-CO(III)]\rightarrow^{e^-}[Co(III)-O_2-Co(II)]\rightarrow^{e^-}[Co(II)-O_2-Co(II)]\rightleftarrows^{e^-}[Co(II)+Co(II)+O_2{\cdot}^-]\rightleftarrows^{e^-}[Co(II)+Co(I)+O_2{\cdot}^-]\rightleftarrows^{e^-}[Co(I)+Co(I)+O_2{\cdot}^-]$$</TEX>.
- keywords
- Schiff base cobalt(II) complex, Catalytic effect
- Downloaded
- Viewed
- 0KCI Citations
- 0WOS Citations
Other articles from this issue
- Studies on the Determination of Heavy Metal Ions by Flow Injection, the Photochemical Characterization and Polymerization of Eight-Coordinated Complex(Part I): Spectrophotometric Determination of Uranium and Thorium Ions by Flow Injection Analysis using Chrome Azurol S in the Presence of Surfactant
- The role of matrix modifier and for the determination of cadmium in blood by graphite furnace atomic absorption spectrometry
- Determination of 2-Mercapto-1-methyl-imidazole in Antithyroid Drug by Differential Pulse Polarography
- Determination of Thioglycolic acid in the presence of Copper(II) by Adsorptive Stripping Voltammetry
- A Selectivity Character for the Phase Transfer Reactions of Alcohols by Tetra-n-Butyl Ammonium Chloride
- Fluorescence Signal Analysis of Mixed Rare Earth Elements by Nonlinear Fitting Method
- Spectroscopic Characterization on the Aggregation Behavior of Pyronin G with Tetraphenylborate anion
- Studies on Electroanalytical Chemistry for the Oxygen Adducted Tetradentate Schiff base Cobalt(III) Complexes in Pyridine Solution
- A polymer pH-Selectrode Based on Tribenzylamine as Neutral Carrier
- Fundamental Studies of Gas-jet Assisted Radio Frequency Glow Discharge Atomic Absorption Spectrometry
- Ion-Selective Electrodes for the Determination of Alverine
- Electrochemical Corrosion Characteristics of the Iron-based Damping Alloy
- A Study on the Lime Stabilization of Livestock Waste
- Determination of Zinc in the Scalp Hair of the Reumatoid Arthritis Patients
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.