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- E-ISSN 2288-8985
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Studies on Solvent Extraction and Analytical Application of Metal Dithiocarbamate Complexes(II). Extraction Equilibria of Metal-Dibenzylammonium dibenzyldithiocarbamate Complexes
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1996, v.9 no.3, pp.221-234
Lee,
J., Choi,
J., Choi,
H., &
Kim,
Y.
(1996). Studies on Solvent Extraction and Analytical Application of Metal Dithiocarbamate Complexes(II). Extraction Equilibria of Metal-Dibenzylammonium dibenzyldithiocarbamate Complexes. Analytical Science and Technology, 9(3), 221-234.
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Abstract
Basic studies for the effective extraction of dibenzylammonium dibenzyldithiocarbamate(DBADBDC) complexes of Ag(I), Pd(II), Au(III) and Pt(IV) into chloroform have been conducted. The effects of pH on the extraction of ligand itself and metal cemplexes showed that DBADBDC itself was uniformly extracted in the pH range of 2~9 and metal complexes were effectively extracted at the pH range as follows. That is, Ag(I) : in an acidic aqua medium, Pd(II) : > 4, Au(III) : wide range, and Pt(IV) : > 3. The distribution ratio and extractabilities were obtained from the partition and extraction equilibria of metal-DBDC complexes between aqueous solution and chloroform. Ag(I) : log D
- keywords
- Dibenzylammonium dibenzyldithiocarbamate(DBADBDC), Extraction, Distribution ratio, Extraction constant, Noble metal ion
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