- P-ISSN 1225-0163
- E-ISSN 2288-8985
- Apply for Authority
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
Synthesis and Properties of Polydentate Schiff Base Ligands having <TEX>$N_nO_2$</TEX> (n
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1998, v.11 no.6, pp.440-447
Kim,
S., Shin,
Y., &
Park,
S.
(1998). Synthesis and Properties of Polydentate Schiff Base Ligands having <TEX>$N_nO_2$</TEX> (n. Analytical Science and Technology, 11(6), 440-447.
- Downloaded
- Viewed
Abstract
Polydentate Schiff base ligands 5-Br-BSDT(bis(5-bromosalicylaldehyde)diethylenetriamine) having <TEX>$N_3O_2$</TEX> atoms, 5-Br-BSTT(bis(5-bromosalicylaldehyde)triethylenetetramine) having <TEX>$N_3O_2$</TEX> atoms, 5-Br-BSTP(bis(5-bromosalicylaldehyde)tetraethylenepentamine) having <TEX>$N_3O_2$</TEX> atoms were synthesized. Stability constants of the complexes between these ligands and the metal ions such as Cu(II), Ni(II) and Zn(II) were measured in DMSO by a polarographic method. It was observed that all metal(II) ions employed in this study formed 1 : 1 complexes with Schiff base ligands. Stability constants for the ligands were in the order of Cu(II)>Ni(II)>Zn(II), and for complex formation were in the order of 5-Br-BSTP>5-Br-BSTT>5-Br-BSDT according to the increasing in the number of donor atoms. Both enthalpy and entropy changes are obtained in negative valves. Exothermicity for the complex formation indicated tight binding between the ligands and metal ions. The negative entropy change would be related to the fact that solvent molecules are strongly interacting with the metal complexes.
- keywords
- Schiff base ligand, donor atoms, protonation constant
- Downloaded
- Viewed
- 0KCI Citations
- 0WOS Citations
Other articles from this issue
- Review : Characterization of Semiconductor Using Neutron Activation Analysis - 2 - Manufacturing Process and Surface Depth Profile Analysis
- Hydrophobic Interaction of Sodium Naphthalene Derivatives in <TEX>$H_2O$</TEX>-MeOH Mixture Solutions and in Surfactant Solutions
- Separation and Purification for the Determination of Zirconium and Its Isotopes in PWR Spent Nuclear Fuels
- Sensitive Fluorogenic Derivatization Method for Bile Acids by Dansyl Cadaverine
- Determination of Ginseng Saponins by Reversed-Phase High Performance Liquid Chromatography
- Chemistry : Determination of Ginseng Saponins by Reversed - Phase High Performance Liquid Chromatography
- Synthesis and Properties of Polydentate Schiff Base Ligands having <TEX>$N_nO_2$</TEX> (n
- Determination of NaOH, <TEX>$Na_2CO_3$</TEX> and <TEX>$Na_2S$</TEX> Concentration in a Naphtha Cracking Process by FT-NIR Spectroscopy
- Synthesis of Chelating Adsorbent (2,2'-Iminodibenzoic Acid-crosslinked Chitosan) and Adsorptivity of Pb(II), Cu(II), Cd(II)
- Electrocatalytic Effect of Dioxygen Reduction at Glassy Carbon Electrode Modified with Schiff Base Co(II) Complexes
- Determination of Gasoline Brands by the Comparison of Infrared Spectra of Polymeric Dispersants
- Preparation of Standard Phosphatidylcholine Hydroperoxide for Chemiluminescence-HPLC Assay
- Studies on the Distribution of Polyphenols in the Parts of Quercus acutissima
- A Study of EPMA Analysis for Nitric Acid Insoluble Alloys
- The Effect of High Concentration Cation Matrix on the Analysis of the Low Anion Concentration in Suppressed Ion Chromatography
- A Study on the Analytical Method of Trace Metal Ions in Sea Water by Inductively Coupled Plasma - Mass Spectrometry using Solid-Liquid Extraction Technique
- Characterization of Semiconductor Using Neutron Activation Analysis-II - Manufacturing Process and Surface Depth Profile Analysis -
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.