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Synthesis and Structural Analysis of a New Layered Cobalt(II) Compound with p-Toluenesulfonic Acid : <TEX>$[Co(H_2O)_6](CH_3C_6H_4SO_3)_2$</TEX>
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2000, v.13 no.4, pp.534-538
Kim,
C., &
Lee,
S.
(2000). Synthesis and Structural Analysis of a New Layered Cobalt(II) Compound with p-Toluenesulfonic Acid : <TEX>$[Co(H_2O)_6](CH_3C_6H_4SO_3)_2$</TEX>. Analytical Science and Technology, 13(4), 534-538.
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Abstract
The title compound, <TEX>$[Co(H_2O)_6](CH_3C_6H_4SO_3)_2$</TEX>, has been prepared and characterized by X-ray crystallography. The crystal structure of the compound demonstrates a layered material constituted by hexaaquacobalt (II) cations and p-toluenesulfonate anions. Geometrical environment of the cobalt atom is octahedrally coordinated by water molecules. The p-toluenesulfonate anions are arranged with the sulfonate groups turned toward opposite side of the layer, alternately. The layered structure is stabilized by the hydrogen bondings between the ligated water molecules and the anionic sulfonate oxygen atoms.
- keywords
- cobalt compound, p-toluenesulfonic acid, layered material, structure analysis
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