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  • 한국과학기술정보연구원(KISTI) 서울분원 대회의실(별관 3층)
  • 2024년 07월 03일(수) 13:30
 

  • P-ISSN1225-0163
  • E-ISSN2288-8985
  • SCOPUS, ESCI, KCI

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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

2-Mercaptobenzothiazole이 흡착된 Silica Gel을 이용한 자연수 중의 코발트(II)의 농축 및 정량

Preconcentration and Determination of Cobalt(II) in Natural Waters using Silica Gel Loaded with 2-Mercaptobenzothiazole

분석과학 / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2004, v.17 no.6, pp.532-535
최희선 (동해대학교)
최종문 (한중대학교)
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Abstract

A method on the determination of Co(II) after adsorbing of Co(II) on 2-mercaptobenzothiazole-loaded silica gel was studied. The conditions on the separation of Co(II) such as pH of solution, the amount of 2-mercaptobenzothiazole, the flow rate for adsorption, and the desorption solvent were optimized to 9.0, 0.05 g, <TEX>$10mL\;min^{-1}$</TEX> and 1 M <TEX>$HNO_3$</TEX> in ethanol, respectively. Under these optimum conditions, the calibration curve of Co(II) was obtained over concentration range of <TEX>$2{\sim}120ng\;mL^{-1}$</TEX>. The detection limit was <TEX>$0.6ng\;mL^{-1}$</TEX>. Recovery yields of Co(II) in various natural water samples were more than 90%.

keywords
cobalt, 2-mercaptobenzothiazole, silica gel, preconcentration


참고문헌

1

(1963.) Standard Methods of Chemical Analysis,

2

(1998.) Principles of Instrumental Analysis, Saunders College Publishing

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