- P-ISSN 1225-0163
- E-ISSN 2288-8985
- Log In/Sign Up
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
Studies on the Sorption Behavior of Some Metal Ions using XAD-16-Chromotropic Acid Chelating Resin
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2004, v.17 no.6, pp.454-463
&
(2004). Studies on the Sorption Behavior of Some Metal Ions using XAD-16-Chromotropic Acid Chelating Resin. Analytical Science and Technology, 17(6), 454-463.
- Downloaded
- Viewed
Abstract
The sorption behavior of some metal ions on XAD-16-CTA chelating resin was investigated by batch method. The sorption of chelating resin was highly selective for Hf(Ⅳ), Zr(Ⅳ) and Th(Ⅳ) at pH 3.0 ∼ 6.0 and the maximum sorption capacity of Zr(IV) ion was 0.81 mmol/g. It was successfully applied to the separation of several rare metal ions from mixed metal solutions by using CDTA, EDTA, NTA and NH4F as masking agent. The elution order of metal ions obtained from breakthrough capacity and the overall capacity at pH 4.0 was Zr(Ⅳ)〉Th(Ⅳ)〉Hf(Ⅳ)〉U(Ⅵ)〉Cu(Ⅱ)〉In(Ⅲ)〉Pb(Ⅱ).Desorption characteristics for metal ions was investigated with desorption agents such as HCl, HNO3, HClO4. 2 M HCl showed high desorption efficiency. Th(Ⅳ) ion can be successfully separated from mixed metal ions by using XAD-16-CTA cheating resin.
- keywords
- XAD-16-CTA chelating resin, breakthrough capacity, overall capacity, desorption
Reference
1
Escobar, V. G, (1998) Appl. Radiot. Isot.,
2
Yokoyama, T, (1999) Anal. Chem.,
3
Ghosh, J. P, (1981) Talanta.,
4
Hiraide, M, (1985) Anal Chim Acta,
5
Hamon, R. F, (1982) Talanta,
6
Tohn, J, (1994) Polymer International,
7
Sarzamini, C, (1989) V. Porta, E. Mentasti,
8
Parrish, J. R, (1997) Anal Chem.,
9
Chanda, M, (1997) Ind. Eng. Chem. Res.,
10
Prasad, B. B, (1995) Bull Chem. Soc. Jpn.,
11
Imal, S, (1983) Anal. Chem.,
12
Brajter, K, (1986) Talanta,
13
Lee, W, (2004) Anal. Sci. & Tech,
14
Ladislav, S, (1991) Collet. Czech. Chem. Commun.,
15
Athavale, V. T, (1967) J. inorg. nucl. Chem.,
Other articles from this issue
- Analytical Methods of Antibiotics in Food and Aqueous Sample
- Method Validation and Uncertainty Estimation for Toluene Measurement in Biological Fluids by HS-GC
- Studies on the Sorption Behavior of Some Metal Ions using XAD-16-Chromotropic Acid Chelating Resin
- Electrochemical behavior and Application of Ruthenium-Cupferron Complex
- Amperometric Determination of Anthracycline Antibiotics with the Mercury Film Thin Layer Flow Cell
- Analysis of Germanium in the Ore Samples by UV-Visible Spectroscopy
- Solvent Extraction of Trace Amount of Ni(II) in Sea Water by using Salen[N,N'-bis(salicylidene)ethylenediamine]
- Consideration of the analytical bias involved in the detection of total volatile organic compounds (TVOC)
- Evaluation of Adsorbent Sampling Methods for Volatile Organic Compoundsin Indoor and Outdoor Air
- A Study on the Measurement of Activity Concentrations of Pu and Am and Their Isotopic Ratios in the Radioactively Contaminated Soil
- Determining Anti-impotence drug-like compounds in Food
- Determination of ethylene glycol in alkali wastewater by gas chromatography/mass spectrometry
- Preconcentration and Determination of Cobalt(II) in Natural Waters using Silica Gel Loaded with 2-Mercaptobenzothiazole
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.