- P-ISSN 1225-0163
- E-ISSN 2288-8985
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- P-ISSN1225-0163
- E-ISSN2288-8985
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Temperature-dependent studies on catalytic hydrosilation of polyalkylsiloxane using NMR
분석과학 / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2017, v.30 no.4, pp.213-219
https://doi.org/10.5806/AST.2017.30.4.213
(충남대학교)
(한국화학연구원)
(한국화학연구원)
(한국화학연구원)
(한국화학연구원)
(한국화학연구원)
(한국화학연구원)
(한국화학연구원)
(한국화학연구원)
(한국화학연구원)
(한국화학연구원)
설혜원,
이태희,
임은수,
노예철,
김정혁,
&
김정권.
(2017). . 분석과학, 30(4), 213-219, https://doi.org/10.5806/AST.2017.30.4.213
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Abstract
Polyalkylsiloxane has been spotlighted in pressure-sensitive adhesive (PSA) application due to excellent physical properties and good biocompatibility. Thermal behaviour of polyalkylsiloxane mixtures, such as thermal stability and heat flow, were studied using TG-DTA during catalytic hydrosilation. To understand reaction kinetics of cross-linking, catalytic hydrosilation of polyalkylsiloxane was monitored using variable temperature nuclear magnetic resonance (VT-NMR) as increased temperature. The formation of cross-linking bond Si-CH2-CH2-Si was directly observed using distortionless enhanced by polarization transfer (DEPT) technique. Successfully polyalkylsiloxane PSA samples exhibited excellent adhesion properties by cross-linking reaction.
- keywords
- VT-NMR, catalytic hydrosilation, cross-linking, polyalkylsiloxane, pressure-sensitive adhesive
참고문헌
1
1. Sue Mecham, A. Sentman, and M. Sambasivam, J. Appl. Polym. Sci., 116(6), 3265-3270 (2010).
2
2. G. Tolia and S. Kevin Li, Eur. J. Pharm. Biopharm., 82(3), 518-525 (2012).
3
3. I. Webster, Int. J. Adhes. Adhes., 17(1), 69-73 (1997).
4
4. X. Thomas., Silicone Adhesives in Healthcare Applications, Dow Corning Literature, Dow Corning Corporation:Midland, Michigan (2003).
5
5. F. De Buyl, Int. J. Adhes. Adhes., 21(5), 411-422 (2001).
6
6. C. A. Dahlquist, Pressure-sensitive adhesives, Marcel Dekker (1969).
7
7. I. Khan, and B. T. Poh, J. Polym. Environ., 19(3), 793-811 (2011).
8
8. E. Delebecq, and F. Ganachaud, ACS Appl. Mater. Interfaces, 4(7), 3340-3352 (2012).
9
9. M. Kovermann, K. Saalwächter, and W. Chassé, J. Phys. Chem. B, 116(25), 7566–7574 (2012).
10
10. S. Vengatesan, D. Vasudevan, and S. Radhakrishnan, Colloid Polym. Sci., 293(12), 3439-3448 (2015).
11
11. S. K. Sahoo, W. Liu, L. A. Samuelson, J. Kumar, and A. L. Cholli, Macromolecules, 35(27), 9990-9998 (2002).
12
12. D. M. Doddrell, D. T. Pegg, and M. R. Bendall, J. Magn. Reson., 48(2), 323-327 (1982).
13
13. H. Uehara, M. Saitoh, R. Morita, E. Akiyama, and T. Yamanobe, Macromolecules, 47(3), 888-896 (2014).
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