- P-ISSN 1225-0163
- E-ISSN 2288-8985
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- P-ISSN1225-0163
- E-ISSN2288-8985
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The Influence of Vanadium Addition on Fracture Behavior and Martensite Substructure in a Ni-36.5at.%Al Alloy
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1992, v.5 no.2, pp.203-211
Kim,
Y. D., Choi,
J., &
Wayman,
C.
M.
(1992). The Influence of Vanadium Addition on Fracture Behavior and Martensite Substructure in a Ni-36.5at.%Al Alloy. Analytical Science and Technology, 5(2), 203-211.
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Abstract
Fracture behavior and martensite substructure of Ni-36.5at.%Al alloy were investigated with the addition of vanadium which is known as scavenging element of grain boundary. The fracture surfaces were examined by scanning electron microscopy and the EDX spectrometer was applied for composition analysis of fracture surfaces. The substructure of martensite was studied by transmission electron microscopy. By addition of vanadium, fracture surfaces show mixed modes of intergranular and transgranular fracture and more Al content is found on the grain boundaries. For Ni-36.5at.%Al alloy, the planar faults observed in the martensite plates are the internal twins. By increasing the vanadium content, the modulated structure with stacking faults and dislocations dominates while the twinned martensite disappears. The stacking fault is determined to be extrinsic due to the substitution of V for Al. It is concluded that the segregation of sulfur on the high-energy state stacking fault area suppresses the intergranular fracture.
- keywords
- NiAl, Martensite substructure, Vanadium addition
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