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Synthesis, Protonation Constants and Stability Constants for <TEX>$Co^{2+}$</TEX>, <TEX>$Ni^{2+}$</TEX>, <TEX>$Cu^{2+}$</TEX>, and <TEX>$Zn^{2+}$</TEX> Ions of 1,15-bis(2-pyridyl)-2,5,8,11,14-pentaazapentadecane
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1996, v.9 no.4, pp.411-415
Kim,
S., Kim,
J., Jung,
W., &
Chung,
K.
(1996). Synthesis, Protonation Constants and Stability Constants for <TEX>$Co^{2+}$</TEX>, <TEX>$Ni^{2+}$</TEX>, <TEX>$Cu^{2+}$</TEX>, and <TEX>$Zn^{2+}$</TEX> Ions of 1,15-bis(2-pyridyl)-2,5,8,11,14-pentaazapentadecane. Analytical Science and Technology, 9(4), 411-415.
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Abstract
The new potentially heptadentate <TEX>$N_7$</TEX> ligand 1, 15-bis(2-pyridyl)-2, 5, 8, 11, 14-pentaazapentadecane(pytetren) has been synthesized and characterized by EA, IR, NMR, and mass spectrometry. Its proton association constants (log <TEX>$K{_H}^n$</TEX>) and stability constants(log <TEX>$K_{ML}$</TEX>) for <TEX>$Co^{2+}$</TEX>, <TEX>$Ni^{2+}$</TEX>, <TEX>$Cu^{2+}$</TEX>, and <TEX>$Zn^{2+}$</TEX> ions were determined at 298.1K and ionic strength
- keywords
- protonation constant, stability constant, potentiometry
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