- P-ISSN 1225-0163
- E-ISSN 2288-8985
- Apply for Authority
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
The Extraction and Derivatization of Organotins in Water Sample by Gas Chromatograph/Mass Spectrometer
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2000, v.13 no.5, pp.636-645
Hong,
J., Lee,
K., Pyo,
H. S., Park,
S., &
Lee,
W.
(2000). The Extraction and Derivatization of Organotins in Water Sample by Gas Chromatograph/Mass Spectrometer. Analytical Science and Technology, 13(5), 636-645.
- Downloaded
- Viewed
Abstract
A method is described for the determination of organotins in water samples by GC/MS. Optimized derivatization methods for ethylation and hydrogenation of organotins were surveyed according to various reaction conditions such as time, pH and concentration of reagents. The organotins were extracted with n-hexane in presence of 0.1% tropolone and hydrogenated with sodium borohydride. Extraction recoveries of organotins with hydrogenation were in the range of 61-112%. After ethylation, organotins in water samples were extracted by liquid-liquid extraction (LLE) and solid-phase extraction (SPE). Using LLE, extraction recoveries were in the range of 74-113%. The recoveries ranged from 61-97% in the case of SPE with styrene-divinylbenzene copolymers. Method detection limits of hydrogenated and ethylated organotins ranged from 0.05 to 0.5 ng/ml and from 0.02 to 0.05 ng/ml, respectively.
- keywords
- organotin, LLE, SPE, derivatizations, GC/MS
- Downloaded
- Viewed
- 0KCI Citations
- 0WOS Citations
Other articles from this issue
- Uncertainty in Measurements and Analyses ( 4 ) - Expression and Calculation of Uncertainty by the International Rule ( GUM ) -
- The Hydrolysis Measurement of Cyclodextrins Using FTIR-ATR Spectrometry
- Properties of Mononuclear and Binuclear Cu(II) Schiff Base Complexes and Oxidation of Ascorbic Acid
- A Study on the Standards for Xe Analysis by Wavelength Dispersive X-ray Spectrometer (WDS) of Electron Probe Micro Analysis (EPMA)
- Liquid Phase Adsorption of Activated Carbon Fibers
- A Study on the Separation of Neodymium from the Simulated Solution of <TEX>$U_3Si/Al$</TEX> Spent Nuclear Fuel
- Simultaneous Determination of Biliary Free and Phospholipid Fatty Acids Using Gas Chromatography-Mass Spectrometry
- Determination of La in <TEX>$U_3Si/Al$</TEX> Spent Nuclear Fuel by Ion Chromatography-Inductively Coupled Plasma-Mass Spectrometry
- Preconcentration and Determination of Trace Cobalt and Nickel by the Adsorption of Metal-PDC Complexes on the Anion-Exchange Resin Suspension
- Determination of Phthalate Esters and Adipate in Water and Sediment Samples
- Homogeneous Enzyme-linked Binding Assay for Mistletoe Lectin I Based on the Mistletoe Lectin I/D-galactose Interaction
- Effects of Some Crude Drug Extracts on the Brain Neurotransmitters in the Ethanol-Treated Rats
- The Extraction and Derivatization of Organotins in Water Sample by Gas Chromatograph/Mass Spectrometer
- Photocatalytic Destruction of a Mordant Yellow-12 Using Rutile-<TEX>$TiO_2$</TEX>
- Degradation of Humic Acids by Ozone/high pH, Ozone/Hydrogen Peroxide and Ozone/Hydrogen Carbonate System
- Formation of Hydrogen Peroxide by the Ozonation of Aqueous Humic Acid
- Determination of Polybrominated Biphenyls in Biota Samples Using Gas Chromatography/Mass Spectrometry
- Certification and Quality Control of the Official Test Facilities of Dioxins in Korea
- The Volatile Organic Compounds Released from PVC Food Wrapping Film at Normal Use Condition
- Uncertainty in Measurements and Analyses(IV) - Expression and Calculation of Uncertainty by the International Rule(Gum) -
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.