- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
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Crystallographic Analysis of Ar Ecapsulate within Cs3-A Zeolite
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2002, v.15 no.6, pp.540-549
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(2002). Crystallographic Analysis of Ar Ecapsulate within Cs3-A Zeolite. Analytical Science and Technology, 15(6), 540-549.
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Abstract
The arrangement of encapsulated Ar atoms in the molecular-dimensioned cavities of fully dehydrated zeolite A of unit-cell composition <TEX>$Cs_3Na_8HSi_{12}Al_{12}O_{48}$</TEX> (<TEX>$Cs_3$</TEX>-A) has been studied crystallographically to probe the confinement effect of guest species in microporous environment. Atoms of Ar were encapsulated in the cavities of <TEX>$Cs_3$</TEX>-A by treatment with 410 atm of Ar at <TEX>$400^{\circ}C$</TEX> for two days, followed by cooling at room temperature. The crystal structure of <TEX>$Cs_3Na_8H$</TEX>-A(4Ar) (<TEX>$P_e$</TEX>
- keywords
- zeolite A, encapsulation, argon cluster, confinement effect
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