- P-ISSN 1225-0163
- E-ISSN 2288-8985
- Apply for Authority
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
The Study on the Mechanism for Oxidation Reaction of Boratabenzne by Cyclic Voltammetry
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2002, v.15 no.6, pp.550-555
(2002). The Study on the Mechanism for Oxidation Reaction of Boratabenzne by Cyclic Voltammetry. Analytical Science and Technology, 15(6), 550-555.
- Downloaded
- Viewed
Abstract
The oxidation mechanism of boratabenzene was studied. As a model compound the ferrocene analogue (<TEX>${\eta}^6$</TEX>-1-Methylboratabenzene)(<TEX>${\eta}^5$</TEX>-Pentamethylcyclopentadiennyl)iron 3 was chosen. The complex underwent irreversible oxidation in the presence of ortho proton on the ring and a methyl group on the boron atom in methanol medium. Chemical oxidations with <TEX>$Hg(OAc)_2$</TEX>, <TEX>$HgSO_4$</TEX>, <TEX>$Cu(OH)_2$</TEX>, <TEX>$AgCF_3SO_3$</TEX> or <TEX>$FeCl_3$</TEX> in MeOH gave, via a transition state [3], at first the derivates 6 and 7, which were converted to each 8 and 9.
- keywords
- Cyclic Voltammetry, Reaction mechanism, Boratabenzene, Oxidation, Complex
Other articles from this issue
- Accumulation of Organonitrogen Pesticides in Fishes and Amphibians from the Basin of Major Rivers of S. Korea
- Fundamental study of electrolyte cathode atomic discharge for development of on-line monitoring system
- The Fundamental Studies and Development of the Modified See-Through Hollow Cathode Glow Discharge Cell for Atomic Emission Spectrochemical Analysis
- Determination of Inorganic Elements in women Blood Serum using Instrumental Neutron Activation Analysis
- The Fundamental Studies and Development of Modified Electrothermal Vaporization Hollow Cathode Glow Discharge Cell
- Analysis of Trace Elements in Mud Flat with Neutron Activation Analysis (NAA) and Atomic Spectroscopy
- Trace Analysis of Racemic Isomers of Flurbiprofen in Human Urine using Column Switching-HPLC
- Analysis of Trace odorous compounds
- Crystallographic Analysis of Ar Ecapsulate within Cs3-A Zeolite
- The Study on the Mechanism for Oxidation Reaction of Boratabenzne by Cyclic Voltammetry
- Characteization on Air Pollution of Gunpo City by Measurement of VOCs in Air
- Characterization of Unburned Carbon Particles from Fly Ash Using SEM
- Carbohydrate Drug (Acarbose) Analysis using by the On-line HPLC/Electrospray
- Confirmation of reterence value using uncertainty of multiple measurements
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.