- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
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Photoluminescence analysis of Lewis base coordinate europium(III) β-diketonate complex
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2015, v.28 no.3, pp.204-211
https://doi.org/10.5806/AST.2015.28.3.204
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(2015). Photoluminescence analysis of Lewis base coordinate europium(III) β-diketonate complex. Analytical Science and Technology, 28(3), 204-211, https://doi.org/10.5806/AST.2015.28.3.204
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Abstract
란탄족 착물은 독특한 발광 특성으로 인하여 많은 연구가 되고 있는 물질이다. 유로피움(III) β- 디케토네이트 착물에 아민계열 또는 포스핀옥사이드계열 리간드를 추가로 배위 결합시켜 발광 효율을비교하였으며, 아민계열 배위보다는 발광 효율 증진에는 포스핀옥사이드 계열이 더 좋은 추가 리간드임을확인하였다. 그 중에서도 트리옥틸포스핀 옥사이드를 배위시켰을 때 가장 높은 발광효율이 관찰되었다. 추가로 배위될 수 있는 트리옥틸포스핀 옥사이드의 당량을 확인하기 위해서 31P-NMR과 photoluminescence 를 분석하였다. 유로피움(III) β-디케토네이트 화합물은 리간드의 입체장애에 따라 트리옥틸포스핀 옥사이드의 배위 당량은 1개 또는 2개가 가능함을 확인하였다.
- keywords
- europium β, -diketonate, EuFOD, lanthanide, down shifting, trioctylphosphine oxide
Reference
1
1. M. Haase and H. Schaefer, Angew. Chem., Int. Ed., 50, 5808-5829 (2011).
2
2. A. Shalav, B. S. Richards, T. Trupke, K. W. Kramer and H. U. Gudel, J. Appl. Phys. Lett., 86, 013505 (2005).
3
3. M. Pollnau, D. R. Gamelin, S. R. Luthi, H. U. Luthi and M. P. Hehlen, Phys. Rev., 61, 3337-3346 (2000).
4
4. C. Strumpel, M. McCann, G. Beaucarne, V. Arkhipov, A. Slaoui, V. Svrcek, V. Svrcek, del C. Canizo and I. Tobias, Sol. Energy Mater. Sol. Cells., 91, 238-249 (2007).
5
5. B. S. Richards, Sol. Energy Mater. Sol. Cells., 90, 2329-2337 (2006).
6
6. T. Trupke, M. A. Green and P. Wurfel, J. Appl. Phys., 92, 1668-1674 (2002).
7
7. J. Chrysochoos, J. Chem. Phys., 60, 1110-1112 (1974).
8
8. M. Montalti, L. Prodi, N. Zaccheroni, L. Charbonniere, L. Douce and R. Ziessel, J. Am. Chem. Soc., 123, 12694-12695 (2001).
9
9. G. Blasse, J. Chem. Phys., 45, 2356-2360 (1966).
10
10. B. L. An, J. X. Shi, W. K. Wong, K. W. Cheah, R. H. Li, Y. S. Yanf and M. L. Gong, J. Lumin, 99, 155-160 (2002).
11
11. K. Binnemans, Chem. Rev., 109, 4283-4374 (2009).
12
12. H. R. Li, J. Lin, H. J. Zhang, L. S. Fu, Q. G. Meng and S. B. Wang, Chem. Mater., 14, 3651-3655 (2002).
13
13. O. Laporte and W. F. Meggers, J. Optical Society Am, 11, 459-462 (1925).
14
14. S. I. Weissman, J. Chem. Phys., 10, 214-217 (1942).
15
15. A. Beeby, I. M. Clarkson, R. S. Dickins, S. Faulkner, D. Parker, L. Royle, A. S. de Sousa, J. A. Gareth Williams and M. Woods, J. Chem. Soc. Perkin Trans., 2, 493-503 (1999).
16
16. A. I. Voloshin, N. M. Shavaleev and V. P. Kazakov, J. Luminescence., 93, 191-197 (2001).
17
17. A. H. Bruder, S. R. Tanny, H. A. Rockefeller and C. S. Springer, Inorg. Chem., 13, 880-885 (1974).
18
18. G. Vicentini, L. B. Zinner, J. Zukerman-Schpector and Zinner, K. Coordination Chem. Rev., 196, 353-382 (2000).
19
19. N. B. Lima, S. M. Goncalves, S. A. Junior and A. M. Simas, Sci. Reports., 3, 2395-2302 (2013).
20
20. L. B. Melby, N. J. Rose, E. Abramson and J. C. Caris, J. Am. Chem. Soc., 86, 5117-5125 (1964).
21
21. S. M. Mattson, E. J. Abramson and L. C. Thomson, J. less-common Metals., 112, 373-380 (1985).
22
22. A. T. Kandil and K. Farah, J. Inorg. Nucl. Chem., 42, 1491-1494 (1980).
23
23. H. Iwanaga, A. Amano, F. Furuya and Y. Yamasaki, Jpn. J. Apply. Phys., 45, 558-562 (2006).
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