- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
Home > Article Detail
Analysis of volatile compounds and metals in essential oil and solvent extracts of Amomi Fructus
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2015, v.28 no.6, pp.436-445
https://doi.org/10.5806/AST.2015.28.6.436
&
(2015). Analysis of volatile compounds and metals in essential oil and solvent extracts of Amomi Fructus. Analytical Science and Technology, 28(6), 436-445, https://doi.org/10.5806/AST.2015.28.6.436
- Downloaded
- Viewed
Abstract
Amomi Fructus with anti-oxidative activity was chosen and essential oil was obtained by SDE (simultaneous distillation extraction), and 39 constituents were determined by GC-MS (gas chromatography-mass spectrometry). Major components were camphor, borneol acetate, borneol, D-limonene and camphene. Three solvent extracts such as hexanes, diethyl ether and methylene chloride from Amomi Fructus were obtained. These were analyzed by GC-MS and 4 more constituents were identified in addition to 39 components discovered in essential oil. Five major components such as camphor, borneol acetate, borneol, D-limonene and camphene were also detected, however the relative peak percents of those components were different from those of constituents in essential oil. To estimate the kind and the amount of materials evaporated at certain temperature and conditions from essential oil and solvent extracts, dynamic headspace apparatus was used and materials evaporated and trapped at certain conditions were analyzed by GC-MS. Recovery yield of SDE method from Amomi Fructus was measured by using camphor and standard calibration solution of camphor methanol solution and, the yield was 82.0%. Content of Hg was measured by mercury analyzer and contents of Cd, Pb, Cr, Mn, Co, Ni, Cu and Zn in Amomi Fructus, essential oils and solvent extracts were determined by ICP-MS (Inductively coupled plasma-mass spectrometer). Pb, Cd and Hg were measured in the concentration of 0.72 mg/kg, <0.10 mg/kg and 0.0023 mg/kg, respectively and these were below permission level of purity test. Contents of Mn, Cu and Zn in Amomi Fructus were 213 mg/kg, 8.29 mg/kg and 31.0 mg/kg, respectively and which were relatively higher than other metals such as Cr, Co and Ni. Metals such as Mn (0.65 ~ 9.08 mg/kg), Cu (1.16 ~ 4.40 mg/kg) and Zn (1.10 ~ 3.80 mg/kg) in essential oil and solvent extracts were detected. At this point it is not clear that the metals were cross-contaminated in the course of treating Amomi Fructus or metals were contained in Amomi Fructus. The influence evaluation toward biological model study of these metals in essential oil and solvent extracts will be needed.
- keywords
- Amomi Fructus, simultaneous distillation extraction, essential oil, solvent extraction, dynamic headspace/GC-MS
Reference
1
1. M. Takahashi, A. Yamanaka, C. Asanuma, H. Asano, T. Satou and K. Kokike, Nat. Prod. Commun., 9(7), 1023-1026 (2014).
2
2. T. Satou, S. Murakami, M. Matsuura, S. Hayashi and K. Koike, Nat. Prod. Commun., 5(1), 143-146 (2010).
3
3. L. Lucian, O. Cioanca and M. Hancianu, Phytomedicine, 19(6), 529-534 (2012)
4
4. L. R. Chioca, V. D. C. Antunes, M. M. Ferro, E. M. Losso and R. Andreatini, Life Sci., 92(20-21), 971-975 (2013).
5
5. B. S. Koo, S. I. Lee, J. H. Ha and D. U. Lee, Bio. Pharm. Bull., 27(4) 515-519 (2004).
6
6. V. K. Agnihotri, S. G. Agarwal, P. L. Dhar, R. K. Thappa Baleshwar, B. K. Kapahi, R. K. Saxena and G. N. Qazi, Flavour Fragnance J., 20(6), 607-610 (2005).
7
7. Y. Zhang and Z. Z. Wang, Pharm. Biomed. Anal., 47(1), 213-217 (2008).
8
8. S. Cuia, S. Tan, G. Ouyang, S. Jiang and J. Pawliszyn, J. Chromatog. B, 877(20-21), 1901-1906 (2009).
9
9. E. E. Stashenko and J. R. Martinez, J. Biochem. Biophys. Methods, 70(2), 235-242 (2007).
10
10. S. Y. Oh, H. D. Shin, S. J. Kim and J. Hong, J. Chromatogr. A, 1183(1-2), 170-178 (2008).
11
11. M. S. Kim, T. W. Kang, H. Pyo, J. Yoon, K. Choi and J. Hong, J. Chromatogr. A, 1208(1-2), 25-33 (2008).
12
12. M. Benzo, G. Gilardoni, C. Gandini, G, Caccialanza, P. V. Finzi, G. Vidari, S. Abdo and P. Layedra, J. Chromatogr. A, 1150(1-2), 131-135 (2007).
13
13. A. Chaintreau, Flavour Fragnance J., 16(2), 136-148 (2001).
14
14. P. Tatke and Y. Jaiswal, Res. J. Med. Plants, 5(1), 21-31(2011).
15
15. C. Gherman, M. Culea and O. Cozar, Talanta, 53(1), 253-262 (2000).
16
16. Z. O. Mustafa and H. Hilal, Anal. Bioanal. Chem., 379(7-8), 1127-1133 (2004).
17
17. J. L. Hendrick, J. M. Leah and L. T. Taylor, Microchim. Acta., 108(3-6), 115-132 (1992).
18
18. N. K. Dubey, R. Kumar and P. Tripathi, Curr. Sci., 86(1), 37-41 (2004).
19
19. M. M. W. B. Hendriks, L. C. Juarez, D. D. Bont and R. D. Hall, Anal. Chim. Acta., 545(1), 53-64 (2005).
20
20. C. Deng, N. Yao, A. Wang and X. Zhang, Anal. Chim. Acta., 536(1-2), 237-244 (2005).
21
21. C. Deng, A. Wang, A. Shen, D. Fu, J. Chen and X. Chang, J. Pharm. Biomed. Anal., 38(2), 326-331 (2005).
22
22. D.-G., Kim, K.-S. Kim, S.-D. Lee, K. Jung and S-k. Park, Anal. Sci. Technol., 27(2), 114-120 (2014).
23
23. W. H. Cho, Y. Y. Cha, T. H. Baik, B. W. Kim, S. G. Lee, J. S. Yoo, Y. J. Sohn and S. H. Sun, Korean J. Oriental. Physiology & Pathology, 25(3), 489-495 (2011).
Other articles from this issue
- Regulatory mechanism of Angelica Gigas extract powder on matrix metalloproteinases in vitro and in vivo model
- Determination of phenol using solid-phase extraction and HPLC/MSD/FLD in water
- Status of a national monitoring program for environmental radioactivity and investigation of artificial radionuclide concentrations (134Cs, 137Cs and 131I) in rivers and lakes
- Establishment of analytical methods for HPHC list of mainstream cigarette smoke
- A case study of verifying a suicide by carbon monoxide intoxication committed by burning an ignition charcoal briquette
- Improvement of analytical methods for arsenic in soil using ICP-AES
- A study of relationship between stomach cancer and selenoproteins in Korean human blood serum
- Development of a cholesterol biosensor modified with carbon nanotube
- Two dimensional analysis between the performance and the sensitivity of methylnitroimidazole derivatives
- Analysis of volatile compounds and metals in essential oil and solvent extracts of Amomi Fructus
- Evaluation of proficiency and improvement of accuracy on the analysis of brominated flame retardants (PBDEs) in ABS polymer
- Optimization of fractionation efficiency (FE) and throughput (TP) in a large scale splitter less full-feed depletion SPLITT fractionation (Large scale FFD-SF)
- Quantitative analysis of cholesterol in infant formula by isotope dilution liquid chromatography-tandem mass spectrometry
- more
Recommanded Articles
This website recommended the use the Chrome browser for journal website.