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The Infrared Absorption Spectra of Molecular Clusters of Acetonitrile and DMF Diluted by Matrices at 80K
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1992, v.5 no.3, pp.285-294
Kim,
W. H., Jeong,
J. H., &
Jeong,
G.
H.
(1992). The Infrared Absorption Spectra of Molecular Clusters of Acetonitrile and DMF Diluted by Matrices at 80K. Analytical Science and Technology, 5(3), 285-294.
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Abstract
Structures of dimers of the acetonitrile and DMF diluted by carbon-tetrachloride and xenon matrices at 80K were studied with infrared absorption spectroscopy. Sample and matrix materials were codeposited onto a KBr cold trapping window. Infrared absorption spectra of pure samples and diluted samples were compared to explain the structures of dimers. The acetonitrile dimer showed the antiparallel shape and the DMF dimer showed the linear shape. After annealing, the infrared spectrum of the diluted sample showed the same shape with that of the pure sample.
- keywords
- dimer, infrared absprption, acetonitrile, DMF
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