Due to the advent of knowledge-based society and digital environment, libraries especially national libraries are undergoing a transformation and the new concepts, processes and tools for collection development as the heart of libraries are evolving. The purpose of this paper is to propose the direction of hybrid resources development for ensuring sustainable collection and preservation of resources in national libraries. Accordingly, this paper looks about a transformation of national libraries and collection development, and investigates the coverage of national collections based positioning of national libraries through performance indicators in standard, definitions, purposes and missions. It also proposes legal deposit methods of digital resources through the law related library and investigates archiving method of online digital resources including hybrid collection development system in national libraries.